2009

113 Ł. Jaremko, A.M. Kirillov, P. Smoleński, T. Lis, M.F.C. Guedes da Silva, A.J.L. Pombeiro, Synthesis, Characterization and Molecular Structures of the Hybrid Organic-Inorganic Salts of N-alkyl-1,3,5-triaza-7-phosphaadamantane (alkyl = methyl, ethyl) and Tetra(isothiocyanato)cobalt(II). Inorg. Chim. Acta 2009, 362, 1645-1649. http://dx.doi.org/10.1016/j.ica.2008.07.016

112 K.V. Luzyanin, M.F.C. Guedes da Silva, Vadim Yu. Kukushkin, A.J.L.Pombeiro, First example of an imine addition to coordinated isonitrile. Inorg. Chim. Acta 2009, 362, 833-838.  http://dx.doi.org/10.1016/j.ica.2008.02.026

111 J. Lasri, M.F.C. Guedes da Silva, M.N. Kopylovich, S. Mukhopadhyay, M.A.J. Charmier, A.J.L. Pombeiro, Pd^II-Promoted [2+3] Cycloadditions of Pyrrolin N-oxide to Organonitriles. Application of (D⁴-1,2,4-oxadiazoline)-Pd^II Complexes in the Suzuki-Miyaura Reaction. Dalton Trans. 2009, 2210-2216.  http://dx.doi.org/10.1039/b813996b

110 M.N. Kopylovich, J. Lasri, M.F.C. Guedes da Silva, A.J.L. Pombeiro, Single-pot Template Transformations of Cyanopyridines on a PdII Centre: Syntheses of Ketoimine and 2,4-Dipyridyl-1,3,5-Triazapentadiene Palladium(II) Complexes and Their Catalytic Activity for Microwave assisted Suzuki-Miyaura and Heck Cross-Coupling Reactions in Solid Phase. (highlighted as a “hot article”) Dalton Trans. 2009, 3074-3084. http://dx.doi.org/10.1039/b820680e

109 P. Smolenski, L. Benisvy, M.F.C. Guedes da Silva, A.J.L. Pombeiro. Syntheses and Crystal Structures of the First Zinc Complex with 1,3,5-Triaza-7-phosphaadamantane (PTA), [ZnCl₂(PTA)₂], and of the Hybrid Organic-Inorganic Salts of N-Methyl-1,3,5-triaza-7-phosphaadamantane with Tetrahalozinc [PTA-Me]₂[ZnI₂X₂] (X = I, Cl). Eur. J. Inorg. Chem. 2009, 1181-1186. http://dx.doi.org/10.1002/ejic.200801023

108 Zhen Ma, Yanpeng Xing, Mei Yang, Miao Hua, Baoqing Liu, M.F.C. Guedes da Silva, A.J.L. Pombeiro, The double-helicate terpyridine silver(I) compound [Ag₂L₂](SO₃CF₃)₂ (L = 4’-phenyl-terpyridine) as a building block for di- and mononuclear complexes. Inorg. Chim. Acta 2009, 2921-2926. http://dx.doi.org/10.1016/j.ica.2009.01.018

107 A.M.Kirillov, P. Smolenski, L. Benisvy, M.F.C. Guedes da Silva, A.J.L. Pombeiro, Unprecedent Metal-Free C(sp3)-C(sp3) Bond Cleavage: Switching from N-Alkyl- to N-Methyl- 1,3,5-triaza-7-phosphaadamantane. Organometallics 2009, 28, 1683-1687. http://dx.doi.org/10.1021/om801026a

106 K.V. Luzyanin, A.G. Tshovrebov, M.F.C. Guedes da Silva, M. Haukka, A.J.L. Pombeiro,V.Yu. Kukushkin, Metal-mediated [2+3] Cycloaddition of Nitrones to Palladium-bound Isonitriles. Chem. Eur. J., 2009, 15, 5969-5978. http://dx.doi.org/10.1002/chem.200802623

105 N.C.T. Martins, M.F.C. Guedes da Silva, R.Wanke, A.J.L. Pombeiro, Electrocatalytic Reduction of Organohalides Mediated by the Dihalo-Molybdenum Phosphinic Complexes trans-[MoX₂(Ph₂PCH₂CH₂PPh₂)₂] (X = I, Br) – A Mechanistic Study by Cyclic Voltammetry Digital Simulation. Dalton Trans. 2009, 4772-4777. http://dx.doi.org/10.1039/b811393a

104 M. Gajewska, K.V. Luzyanin, M.F.C. Guedes da Silva, Q. Li, Jingrong Cui, A.J.L. Pombeiro, Cyclic Trinuclear Diorganotin(IV)-Complexes – the First Tin Compounds Bearing Oximehydroxamate Ligands: Synthesis, Structural Characterization and High in vitro Cytotoxicity. Eur. J. Inorg. Chem. 2009, 3765-3769. http://dx.doi.org/10.1002/ejic.200900388

103 B.G. Mukhopadhyay, S. Mukhopadhyay, M.F.C. Guedes da Silva, M.A.J. Charmier, A.J. L. Pombeiro, Synthesis of mono- and bis-tetrazolato complexes of Ni(II), Pt(II) and Cu(II) via 1,3- dipolar cycloadditions of 2-cyanopyridines with metal ligated azides in N,N,Oaminoiminophenolato complexes. Dalton Trans. 2009, 4778-4785. http://dx.doi.org/10.1039/b902007a

102 S.M.P.R.M. Cunha, M.F.C. Guedes da Silva, J.J. R. Fraústo da Silva, A.J.L. Pombeiro, Cyanoimide-Bridged, Bi- and Trinuclear, Heterometallic Complexes with na NCN–Mo–NCN Phosphinic Core. Eur. J. Inorg. Chem. 2009, 3966-3971. http://dx.doi.org/10.1002/ejic.200900398

101 A.M. Kirillov, P. Smoleński, Z. Ma, M.F.C. Guedes da Silva, M. Haukka, A.J.L. Pombeiro, Copper(I) Iodide Complexes derived from N-alkyl-1,3,5-Triaza-7-phosphaadamantanes: Synthesis, Crystal Structures, Photoluminescence and Identification of the Unprecedented {Cu₃I₅}^2– Cluster. Organometallics  2009, 28, 6425-6431.  http://dx.doi:10.1021/om900591q

100 L. Benisvy, R. Wanke, M.F.C. Guedes da Silva, A.J.L. Pombeiro, Towards the Functionalisation of the Methine Carbon of a Sterically Hindered Tris(pyrazolyl)methane: Is a Radical Pathway Envisageable- Synthesis and structure of Tetrakis(3,5-dimethylpyrazolyl)methane. Tetrahedron 2009, 65, 9218-9223. http://dx.doi.org/10.1016/j.tet.2009.09.006

99   T.F.S. Silva, G.S. Mishra, M.F. Guedes da Silva, R. Wanke, L.M.D.R.S. Martins, A.J.L. Pombeiro, CuII Complexes Bearing the 2,2,2-tris(1-pyrazolyl)ethanol or 2,2,2-tris(1- pyrazolyl)ethyl methanesulfonate Scorpionates. X-Ray Structural Characterization and Application in the Mild Catalytic Peroxidative Oxidation of Cyclohexane. Dalton Trans. 2009, 9207-9215. http://dx.doi.org/10.1039/b911990f

98A     K.V. Luzyanin, A.G. Tskhovrebov, M.C.Maia, M.F.C. Guedes da Silva, A.J.L. Pombeiro, V.Yu. Kukushkin, Novel Metal-Mediated (M = Pt, Pd) Coupling between Isonitriles and Benzophenone Hydrazone as a Route to Aminocarbene Complexes Exhibiting High Catalytic Activity (M = Pd) in the Suzuki–Miyaura Reaction. Organometallics 2009, 28, 6559-6566.  http://dx.doi.org/10.1021/om900682v

98B J. Lasri, M.F.C. Guedes da Silva, M.N. Kopylovich, B.G. Mukhopadhyay, A.J.L. Pombeiro, Platinum(II)-Promoted [2+3] Cycloaddition of Azide with 4-Cyanobenzaldehyde, a Schiff Base Derivative or Dicyanobenzenes To Give Formyl-, Amino(imino)- or Cyano-Functionalized Tetrazolato Complexes. Eur. J. Inorg. Chem. 2009, 5541-5549. http://dx.doi.org/10.1002/ejic.200900858

2008

97   A.M. Kirillov, Y.Y. Karabach, M. Haukka, M.F.C. Guedes da Silva, J. Sanchiz, M.N. Kopylovich, A.J.L. Pombeiro, Self-assembled Copper(II) Coordination Polymers Derived from Aminopolyalcohols and Benzenepolycarboxylates: Structural and Magnetic Properties. Inorg. Chem., 2008, 47, 162-175.  http://dx.doi.org/10.1021/ic701669x

96   M.V. Kirillova, A.M. Kirillov, M.F.C. Guedes da Silva, M.N. Kopylovich, J.J.R. Fraústo da Silva, A.J.L. Pombeiro, 3D Hydrogen Bonded Metal-Organic Frameworks Constructed from [M(H₂O)₆][M’(dipicolinate)₂].mH₂O (M/M’ = Zn/Ni or Ni/Ni). Identification of Intercalated Acyclic (H₂O)₆/(H₂O)₁₀ Clusters. Inorg. Chim. Acta 2008,  361, 1728-1737. http://dx.doi.org/10.1016/j.ica.2006.12.016

95   M.V. Kirillova, M.L. Kuznetsov, J.A.L. Silva, M.F.C. Guedes da Silva, J.J.R. Fraústo da Silva, A. J.L. Pombeiro, Amavadin and Other Vanadium Complexes as Remarkable Efficient Catalysts for the Single-Pot Conversion of Ethane into Propionic and Acetic Acids. Chem. Eur. J. 2008, 14, 1828-1842. http://dx.doi.org/10.1002/chem.200700980

94   P. Smolenski, A.M. Kirillov, M.F. C. Guedes da Silva, A.J.L. Pombeiro, 1-Methyl-1-azonia-3,5-diaza-7-phosphatricyclo-[3.3.1.13,7]decane Tetrafluoroborate. Acta Cryst. 2008, E64, o556. http://dx.doi.org/10.1107/S1600536808003401

93   A.M. Kirillov, P. Smolenski, M.F.C. Guedes da Silva, M.N. Kopylovich, A.J.L. Pombeiro, Three-dimensional hydrogen-bonded supramolecular assembly in tetrakis(1,3,5-triaza-7-phosphaadamantane)copper(I) chloride hexahydrate. Acta Cryst. 2008, E64, m603-m604. http://dx.doi.org/10.1107/S1600536808008179

92   R.R. Fernandes, A.M. Kirillov, M.F.C. Guedes da Silva, Z. Ma, J.A.L. da Silva, J.J.R. Fraústo da Silva, A.J.L. Pombeiro, An Infinite Two-Dimensional Hybrid Water-Chloride Network, Self-Assembled in a Hydrophobic Terpyridine Iron(II) Matrix. Crys. Grow. & Design 2008, 8, 782-785. http://dx.doi.org/10.1021/cg7010315

91   P. Sgarbossa, M.F.C. Guedes da Silva, A. Scarso, R.A. Michelin, A.J.L. Pombeiro, Lewis acidity of platinum(II)-based Baeyer–Villiger catalysts: An electrochemical approach.Inorg. Chim. Acta 2008, 361, 3247-3253. http://dx.doi.org/10.1016/j.ica.2007.10.050

90   P. Smolenski, C. Dinoi, M.F.C. Guedes da Silva, A.J.L. Pombeiro, Synthesis of the Watersoluble [Rh(Tpms)(CO)(PTA)] Compound, the First Transition Metal Complex Bearing the 1,3,5-triaza-7-phosphaadamantane (PTA) and the Tris(1-pyrazolyl)methane sulfonate (Tpms) Ligands. J. Organometal. Chem. 2008, 693, 2338-2344. http://dx.doi.org/10.1016/j.jorganchem.2008.04.008

89   J. Lasri , M.F.C. Guedes da Silva, M.A. Charmier, A.J.L. Pombeiro, Optically Active Mixed Unsymmetric Imine Platinum(II) Complexes. Utilization of the Liberated Imines to Further Syntheses of Mixed Imine-Diazadiene Complexes and of E-cyanoalkanes. Eur. J. Inorg. Chem. 2008, 3668-3677. http://dx.doi.org/10.1002/ejic.200800343

88   J. Lasri, M.N. Kopylovich, M.F.C. Guedes da Silva, M.A. Charmier, A.J.L. Pombeiro, Metal- Free and PdII-Promoted [2+3] Cycloadditions of a Cyclic Nitrone to Phthalonitriles: Syntheses of Oxadiazolines as well as Phthalamide-PdII and Dihydropyrrolyl-iminoisoindolinone-PdII Complexes with High Catalytic Activity in Suzuki-Miyaura Cross-Coupling Reactions. Chem. Eur. J. 2008, 14, 9312-9322. http://dx.doi.org/10.1002/chem.200800510

87   M. Kirillova, A.M. Kirillov, M.F.C. Guedes da Silva, A.J.L. Pombeiro, Self-assembled Two-dimensional Water-soluble Dipicolinate-Cu/Na Coordination Polymer: Structural Features and Catalytic Activity for the Mild Peroxidative Oxidation of Cycloalkanes in Acid-free Medium. Eur. J. Inorg. Chem. 2008, 3423-3427. http://dx.doi.org/10.1002/ejic.200800355

86   P. Smoleński, S. Mukhopadhyay, M.F.C. Guedes da Silva, M.A.J. Charmier, A.J.L. Pombeiro, New Water-soluble Azido- and Derived Tetrazolato-platinum(II) Complexes with 1,3,5-Triaza-7-phosphaadamantane (PTA). Easy Metal-mediated Synthesis and Isolation, from Aqueous Medium, of 5-Substituted Tetrazoles.       Dalton Trans. 2008, 6546-6555. http://dx.doi.org/10.1039/b808156e

85   S. Mukhopadhyay, J. Lasri, M.F.C. Guedes da Silva, M.A.J. Charmier,   A.J.L. Pombeiro, Activation of C-CN bond of Propionitrile: an Alternative Route to the Syntheses of 5-substituted-1H-Tetrazoles and Dicyano-Platinum(II) Species. Polyhedron 2008, 27, 2883-2888. http://dx.doi.org/10.1016/j.poly.2008.06.031

84   S. Mukhopadhyay, B.G. Mukhopadhyay, M.F.C. Guedes da Silva, J. Lasri, M. A. J. Charmier, A.J.L. Pombeiro,   Pt^II-Promoted [2+3] Cycloaddition of Azide to Cyanopyridines: Convenient Tool toward Heterometallic Structures. Inorg. Chem. 2008, 47, 11334-11341. http://dx.doi.org/10.1021/ic8014223

83   R. Wanke, P. Smolenski, M.F.C. Guedes da Silva, L.M.D.R.S. Martins, A.J.L. Pombeiro, Cu(I) Complexes Bearing the New Sterically Demanding and Coordination Flexible Tris(3-phenyl-1-pyrazolyl)methanesulfonate Ligand and the Water-Soluble Phosphine 1,3,5-Triaza-7-phosphaadamantane or Related Ligands. Inorg. Chem. 2008, 47, 10158-10168. http://dx.doi.org/10.1021/ic801254b

2007

82   A.M. Kirillov, M. Haukka, M.F.C. Guedes da Silva, A.J.L. Pombeiro, Synthesis, Characterization and Redox Behaviour of Mono- and Dicarbonyl Phosphane Rhenium(I) Complexes Bearing N-, N,N- and N,O-Type Ligands. Eur. J. Inorg. Chem. 2007, 1556-1565. http://dx.doi.org/10.1002/ejic.200601026

81   M.V. Kirillova, M.F.C. Guedes da Silva, A.M. Kirillov, J.J.R. Fraústo da Silva, A.J.L. Pombeiro, 3D Hydrogen Bonded Heteroneclear Co^II, Ni^II, Cu^II and Zn^II Aqua Complexes Derived from Dipicolonic Acid. Inorg. Chim Acta. 2007, 360, 506-512. http://dx.doi.org/10.1016/j.ica.2006.07.087

80   J. Lasri, M.A.Januário Charmier, M.F.C. Guedes da Silva, A.J.L. Pombeiro, Direct synthesis of (imine)platinum(II) complexes by iminoacylation of ketoximes with activated organonitrile ligands. Dalton Trans. 2007, 5062-5067. http://dx.doi.org/10.1039/b611341a

79   A.M. Kirillov, P. Smolénski, M.F.C. Guedes da Silva, A.J.L. Pombeiro, The First Copper Complexes Bearing the 1,3,5-Triaza-phosphaadamantane (PTA) Ligand. Eur. J. Inorg. Chem. 2007, 2686-2692. http://dx.doi.org/10.1002/ejic.200601152

78   J. Lasri, M.A.Januário Charmier, M.F.C. Guedes da Silva, A.J.L. Pombeiro, Mixed Unsymmetric Oxadiazoline and/or Imine Platinum(II) Complexes. Dalton Trans. 2007, 3259-3266. http://dx.doi.org/10.1039/b704329e

77   M.T.A.R.S. da Costa, M.F.C. Guedes da Silva, J.J.R. Fraústo da Silva, A.J.L. Pombeiro, Reactions of Bis(phenyldiazenido)rhenium Complex [ReBr₂(NNPh)₂(PPh₃)₂]Br with Carbon Monoxide and Alk-1-ynes. Collect Czech. Chem. Commun. 2007, 72, 599-608.http://dx.doi.org/10.1135/cccc20070599

76   S. Mukhopadhyay, J. Lasri, M.A.J. Charmier, M.F.C. Guedes da Silva, A.J.L. Pombeiro, Microwave Synthesis of Mono- and Bis-Tetrazolato Complexes via 1, 3-Dipolar Cycloaddition of Organonitriles with Platinum(II)-bound Azides. Dalton Trans. 2007, 5297-5304. http://dx.doi.org/10.1039/b709959b

75   S. Bolaño, J. Bravo, J.A. Castro-Fojo, M.M. Rodríguez-Rocha, M.F.C. Guedes da Silva, A.J.L. Pombeiro, L. Gonsalvi, M. Peruzzini, Synthesis, Reactivity, X-ray Crystal Structures and Electrochemical Behaviour of Water-Soluble [Tris(pyrazolyl)borato] ruthenium(II) Complexes of 1,3,5-triaza-7-phosphaadamantane (PTA). (highlighted as one of the most accessed articles in December 2007). Eur. J. Inorg. Chem. 2007, 35, 5523-5532. http://dx.doi.org/10.1002/ejic.200700672

74A     S. Mukhopadhyay, J. Lasri, M.F.C. Guedes da Silva, M.A.J. Charmier, A.J.L. Pombeiro, trans-Bis[5(4-fluorophenyl)tetrazolato]bis(triphenylphosphine) platinum(II)” Acta Crys. 2007, E63, m2656. http://dx.doi.org/10.1107/S1600536807047617

74B T.F.S. Silva, L.M.D.R. Martins, M.F.C. Guedes da Silva*, A.J.L. Pombeiro*, Bis[tris(1-pyrazolyl)methane - k³, N, N, N’, N’’]copper(II) Dichloride Methanol Disolvate. Acta Cryst., 2007, E63, m1979. http://dx.doi.org/10.1107/S1600536807024671

73   A.M. Kirillov, P. Smolenski, M.F.C. Guedes da Silva, A.J.L. Pombeiro, 1-Methyl-1-azonia-3,5-diaza-7-phosphatricyclo-[3.3.1.1]decane 7-oxide triiodide. Acta Crys. 2007, E64, o496–o497. http://dx.doi.org/10.1107/S1600536808001426

2006

72   A.M. Kirillov, M.N. Kopylovich, M.V. Kirillova, E.Yu. Karabach, M. Haukka, M.F.C.Guedes da Silva, A.J.L. Pombeiro, Mild Peroxidative Oxidation of Cyclohexane Catalyzed by Mono-, Di-, Tri-, Tetra- and Polynuclear Copper Triethanolamine Complexes. Ad. Synth. Cat. 2006, 348, 159-174. http://dx.doi.org/10.1002/adsc.200505216

71   N.A. Bokach, M.Haukka, P.Hirva, M.F.C. Guedes da Silva, V.Yu. Kukushkin, A.J.L. Pombeiro, Photoinduced synthesis and electrochemical properties of new ruthenium(mono)bipyridine dialkylcyanamide and propiononitrile complexes. J. Organomet. Chem. 2006, 691, 2368-2377. http://dx.doi.org/10.1016/j.jorganchem.2005.12.064

70   Y.Yu. Karabach, A.M. Kirillov, M.F.C. Guedes da Silva, M.N. Kopylovich, A.J.L. Pombeiro, An Aqua-soluble Copper(II)-sodium 2D Coordination on Polymer with Intercalated Infinite Chains of Decameric Water Clusters. Crys. Grow. Des. 2006, 6, 2200-2203. http://dx.doi.org/10.1021/cg060310e

69   A.M. Kirillov, M. Haukka, M.F.C. Guedes da Silva, J.J.R. Fraústo da Silva, A.J.L.Pombeiro, A Picolinate-N2 Complex of Rhenium, the first Dinitrogen Complex Bearing a Carboxylate or a N,O-Ligand. J. Organomet. Chem. 2006, 691, 4153-4158. http://dx.doi.org/10.1016/j.jorganchem.2006.06.015

2005

68   E.C.B. Alegria, L.M.D.R.S. Martins, M.F.C. Guedes da Silva, A.J.L. Pombeiro, Syntheses and Properties of Re(III) Complexes Derived from Hydrotris(1- pyrazolyl)methanes: Molecular Structure of [ReCl₂(HCpz₃)(PPh₃)][BF₄]”. J. Organometal. Chem. 2005, 690, 1947-1958.http://dx.doi.org/10.1016/j.jorganchem.2004.11.005

67   A.M. Kirillov, M.N. Kopylovich, M.V. Kirillova, M. Haukka, M.F.C. Guedes da Silva, A.J.L. Pombeiro, Multinuclear Copper Triethanolamine Complexes as Selective Catalysts for the Peroxidative Oxidation of Alkanes under Mild Conditions. Angew. Chem., Int. Ed. 2005, 44, 4345-4349; Angew. Chem. 2005, 117, 1119-1123. http://dx.doi.org/10.1002/anie.200500585

66   A.M. Kirillov, M. Haukka, M.F.C. Guedes da Silva, A.J.L. Pombeiro, Preparation and Crystal Structures of Benzoylhydrazido- and -diazenidorhenium Complexes with N,O-Ligands and Their Catalytic Activity Towards Peroxidative Oxidation of Cycloalkane. Eur. J. Inorg. Chem. 2005 2071-2080. http://dx.doi.org/10.1002/ejic.200400991

65   A.I.F. Venâncio, M.F.C. Guedes da Silva, L.M.D.R.S. Martins, J.J.R. Fraústo da Silva, A.J.L. Pombeiro, Allenylidene Iron(II) Complexes and Their Deprotonation, Nucleophilic Addition Reactions, and Cathodic Protonation toward Alkynyl Derivatives: A Chemical and Electrochemical Study. Organometallics  2005, 24, 4654-4665. http://dx.doi.org/10.1021/om050408a