201. L.M.D.R.S. Martins, Catalytic applications of recent metal poly(1H-pyrazol-1-yl)-methane scorpionates. Inorg. Chim. Acta 2022, 541, 121069-121085. - invited: special issue "58th birthday of Claudio Pettinari". https://doi.org/10.1016/j.ica.2022.121069

200. A. Dobrov, D. Darvasiová, M. Zalibera,* L. Bu?inský, I. Pu?kárová, P. Rapta, S. Shova, D.G. Dumitrescu, M.A. Andrade, L.M.D.R.S. Martins,* A.J.L. Pombeiro, V.B. Arion,* Diastereomeric dinickel(II) complexes with noninnocent bis(octaazamacrocyclic) ligands: isomerization, spectroelectrochemistry, DFT calculations and use in catalytic oxidation of cyclohexane. Dalton Trans. 2022, 51, 5151-5167.  https://doi.org/10.1039/d2dt00154c

199. A.P.C. Ribeiro,* B.M. Santos, R.F.C. Faustino, L.M.D.R.S. Martins,* A.J.L. Pombeiro, Microwave-assisted synthesis of heterogenized Re nanoparticles and catalytic oxidation of 1-phenylethanol and reduction of 4-nitrophenol. Catalysts 2022, 12, 285. - invited: special issue: "Energy-Efficient Catalytic Oxidation".  https://doi.org/10.3390/catal12030285

198. A.V. Gurbanov,* M.A. Andrade,* L.M.D.R.S. Martins,* K.T. Mahmudov, A.J.L. Pombeiro, Water-soluble Al(III), Fe(III) and Cu(II) formazanates: synthesis, structure, applications in alkane and alcohol oxidations, New J. Chem. 202246, 5002-5011. https://doi.org/10.1039/D1NJ06211E

197. A.P.C. Ribeiro, I.A.S. Matias, S.A.C. Carabineiro,* L.M.D.R.S. Martins,* Commercial gold complexes supported on functionalised carbon materials as efficient catalysts for the direct oxidation of ethane to acetic acid. Catalysts 2022, 12, 165. - invited: special issue "Catalytic Oxidation of Hydrocarbons". https://doi.org/10.3390/catal12020165

196. A. Martins,* N. Nunes, A.P. Carvalho, L.M.D.R.S. Martins, Zeolites and related materials as catalyst supports for hydrocarbon oxidation reactions. Catalysts 2022, 12, 154 invited: special issue "Porous Materials: Active Phases or Supports in Heterogeneous Catalysis".


195. I.A.S. Matias, P.G. Selfa, A.M. Ferraria, A.M. Botelho do Rego, M.N. Kopylovich, A.P.C. Ribeiro, L.M.D.R.S. Martins, Unprecedented Mechanochemical Synthesis and Heterogenization of a C-Scorpionate Au(III) Catalyst for Microwave-Assisted Biomass Valorization. Nanomaterials 2022, 12, 362. https://doi.org/10.3390/nano12030362


194. M.A. Andrade, L.M.D.R.S. Martins,* Organocatalysis meets hydrocarbon oxyfunctionalization: the role of N-hydroxyimides, Eur. J.Org. Chem., 2021, 4715-4727.  https://doi.org/10.1002/ejoc.202100479

193. A.P.C. Ribeiro,* I.A.S. Matias, P. Zargaran, A.S K. Hashmi, L.M.D.R.S. Martins,* Unprecedented use of NHC gold(I) complexes as catalysts for the selective oxidation of ethane to acetic acid, Materials, 2021, 14, 4294?4302  http://doi.org/10.3390/ma14154294

192. Y.P. Petrenko, K. Piasta, D.M. Khomenko, R.O. Doroshchuk, S. Shova, G. Novitchi, E. Gumienna-Kontecka, L.M.D.R.S. Martins, R.D. Lampeka, An investigation of two copper(II) complexes with a triazole derivative as a ligand: magnetic and catalytic properties, RSC Adv., 2021, 11, 23442 ? 23449. http://doi.org/10.1039/d1ra03107d 

191. M. Sutradhar, M.A. Andrade, S.A.C. Carabineiro, L.M.D.R.S. Martins*, M.F.C. Guedes da Silva, A.J.L. Pombeiro, Oxido- and dioxido-vanadium(V) complexes supported on carbon materials: reusable catalysts for the oxidation of cyclohexane, Nanomaterials, 2021, 11, 1456-1475 - invited paper for the special issue  "Structure and Properties of Functional Nanomaterials"  https://doi.org/10.3390/nano110614

190.  F.M.S. Rodrigues, L.D. Dias, M.J.F. Calvete, T.M.R. Maria, L.M. Rossi, A.J.L. Pombeiro, L.M.D.R.S. Martins, M.M. Pereira, Sequential hydroformylation reactions as a sustainable tool for immobilization of Fe(II)/C-scorpionate onto iron magnetic nanoparticles and acetalization of olefinsCatalysts, 2021, 11, 608, https://doi.org/10.3390/catal11050608

189.  L.M.M. Correia, M.M.A. Soliman, C.M. Granadeiro*, S.S. Balula, L.M.D.R.S. Martins*, A.J.L. Pombeiro, E.C.B.A. Alegria*, Vanadium C-scorpionate supported on mesoporous APTES-functionalized SBA-15 as catalyst for the peroxidative oxidation of benzyl alcohol, Microporous and Mesoporous Materials, 2021, 320, 111111. https://doi.org/10.1016/j.micromeso.2021.111111

188. M.A. Andrade, L.M.D.R.S. Martins,* Selective styrene oxidation to benzaldehyde over recently developed heterogeneous catalysts, Molecules, 2021, 26, 1680-1716. https://doi.org/10.3390/molecules26061680

187. A.P.C. Ribeiro, P. Goodrich, L.M.D.R.S. Martins,* Highly efficient and reusable catalyst to convert CO2 into valuable cyclic carbonatesMolecules 2021, 26, 1089-1099. https://doi.org/10.3390/molecules26041089
186. L.M.D.R.S. Martins, Highlights of the Nanocatalysis in Organic Chemistry, Catalysts 2021, 11, 213-214. - Editorial https://doi.org/10.3390/catal11020213
 Y.Z. Voloshin, S.V. Dudkin, S.A. Belova, D. Gherca, D. Samohvalov, C.-M. Manta, M.A. Lungan, S.M. Meier-Menches, P. Rapta,* D. Darvasiová, M. Malek, A.J.L. Pombeiro, L.M.D.R. Martins,* V.B. Arion, *Spectroelectrochemical Properties and Catalytic Activity in Alkane Oxidation of Hybrid Zr/Hf-Phthalocyaninate-Capped Metal(II) tris-Pyridineoximates, Molecules, 2021, 26, 336 - 356.- invited paper for the special issue "Recent Advances in Modern Inorganic Chemistry". https://doi.org/10.3390/molecules26020336

184. A.P.C. Ribeiro, E. Spada, R. Bertani, L.M.D.R.S. Martins,* Adipic acid route: oxidation of cyclohexene vs. cyclohexane, Catalysts, 2020, 10, 1443-1449. - invited paper for the special issue "Recent Advances in Organometallic Chemistry and Catalysis" http://dx.doi.org/10.3390/catal10121443

183. G.A.O. Tiago, I.A.S. Matias, A.P.C. Ribeiro,* L.M.D.R.S. Martins,* Application of ionic liquids in electrochemistry - recent advances, Molecules, 2020, 25, 5812-5838. - invited paper for the special issue "Exclusive Papers of the Editorial Board Members (EBMs) of the Electrochemistry Section of Molecules" http://dx.doi.org/10.3390/molecules25245812

182. A.F. Cristino, I.A.S. Matias, D.E.N. Bastos, R.G. Santos, A.P.C. Ribeiro*, L.M.D.R.S. Martins*, Glycerol role in nano oxides synthesis and catalysisCatalysts, 2020, 10, 1406 - invited paper. htps://dx.doi.org/doi:10.3390/catal10121406

181. I.A.S. Matias, A.P.C. Ribeiro,* L.M.D.R.S. Martins,* Selective oxidation of ethane to acetic acid catalyzed by a C-scorpionate iron(II) complex: homogeneous vs. heterogeneous, Molecules, 2020, 25, 5642-5654 - invited paper for the special issue  "Advances in C-H Bond Activation and Functionalization" http://dx.doi.org/10.3390/molecules25235642

180. S. Carlotto, G. Casella, L. Floreano, A. Verdini, A.P. C. Ribeiro, L.M.D.R.S. Martins, M. Casarin, Spin State, Electronic Structure and Bonding on C-Scorpionate [Fe(II)Cl2(tpm)] Catalyst: an Experimental and Computational study. Catal. Today, 2020, 358, 403-411, https://dx.doi.org/10.1016/j.cattod.2019.08.010

179. M.A. Andrade, L.M.D.R.S. Martins,New trends in C-C cross coupling reactions: the use of unconventional conditionsMolecules, 2020, 25, 5506-5539. - invited paper for the special issue "Exclusive Papers of the Editorial Board Members (EBMs) of the Materials Chemistry Section of Molecules". http://dx.doi.org/10.3390/molecules25235506

178. I.A.S. Matias, A.P.C. Ribeiro,* A.M. Ferraria, A.M.B. Rego, L.M.D.R.S. Martins,* Catalytic Performance of a Magnetic Core-Shell Iron(II) C-scorpionate under Unconventional Oxidation Conditions, Nanomaterials, 2020, 10, 2111-2124. - invited paper for the special issue "Catalysis by Metal-Oxide Nanostructures". https://doi.org/10.3390/nano10112111

177. M.A. Andrade, A.S. Mestre, A.P. Carvalho,* A.J.L. Pombeiro, L.M.D.R.S. Martins,* The role of nanoporous carbon materials in catalytic cyclohexane oxidationCatal. Today, 2020, 357, 46-55. https://doi.org/10.1016/j.cattod.2019.07.036

176. S.A.C. Carabineiro,* A.P.C. Ribeiro, J.G. Buijnsters,  M. Avalos-Borja, A.J.L. Pombeiro, J.L. Figueiredo, L.M.D.R.S. Martins,* Solvent-free oxidation of 1-phenylethanol catalysed by gold nanoparticles supported on carbon powder materials Catal. Today, 2020, 357, 22-31. https://dx.doi.org/10.1016/j.cattod.2019.06.041

175. E. Pakrieva,* A.P.C. Ribeiro, L.M.D.R.S. Martins,* I.A.S. Matias, S.A.C. Carabineiro,* E. Kolobova, A.J.L. Pombeiro, J.L. Figueiredo, A. Pestryakov, Commercial gold(III) complex supported on functionalized carbon materials as catalyst for cyclohexane hydrocarboxylation, Catal. Today, 2020, 357, 39-45. http://dx.doi.org/10.1016/j.cattod.2019.05.050

174. T.A.G. Duarte, A.P. Carvalho,* L.M.D.R.S. Martins,* Styrene oxidation catalyzed by copper(II) C-scorpionates in homogenous medium and immobilized on sucrose derived hydrocharsCatal. Today., 2020, 357, 56-63. http://dx.doi.org/10.1016/j.cattod.2019.04.044

173. M.A. Andrade, L.M.D.R.S. Martins,* Supported palladium nanocatalysts: recent findings in hydrogenation reactions, Processes, 2020, 8, 1172-1213. - invited paper for the special issue "Advances in Supported Nanoparticle Catalysts", http://dx.doi.org/10.3390/pr8091172

172. M.A. Andrade, L.M.S. Ansari, A.J.L. Pombeiro, A.P. Carvalho, A. Martins,* L.M.D.R.S. Martins,* Fe@Hierarchical BEA zeolite catalyst for MW-assisted alcohol oxidation reaction: a greener approach, Catalysts, 2020, 10, 1029-1041 - invited paper for the special issue "Porous Materials and Catalysts". http://dx.doi.org/10.3390/catal10091029

171. H.M. Lapa, M.F.C. Guedes da Silva, A.J.L. Pombeiro, E.C.B.A. Alegria*, L.M.D.R.S. Martins*, C-scorpionate Au(III) complexes as catalysts for industrially significant toluene oxidation and benzaldehyde esterification reactions,  Inorg. Chim. Acta, 2020, 512, 119881-119891. https://doi.org/10.1016/j.ica.2020.119881

170. A. Dobrov, A. Fesenko, A. Iankov, I. Stepanenko, D. Darvasiová, M. Breza, P. Rapta,* L.M.D.R.S. Martins,* A.J.L. Pombeiro, A. Shutalev,* V.B. Arion, Nickel(II), copper(II) and palladium(II) complexes with bis-semicarbazide hexaazamacrocycles: redox noninnocent behavior and catalytic activity in oxidation and C-C coupling reactions, Inorg. Chem., 2020, 59, 10650-10664. https://dx.doi.org/10.1021/acs.inorgchem.0c01119.

169. A.V. Gurbanov,* L.M.D.R.S. Martins,* M.N. Kopylovich, M. Sutradhar, F.I. Zubkov, K.T. Mahmudov, Armando J. L. Pombeiro*, Mechanochemical synthesis of copper(II) coordination polymers bearing arylhydrazone of acetoacetanilide and their catalytic activity in conversion of acetone to acetic acid, Chem. Select, 2020, 5, 7923-7927. http://dx.doi.org/10.1002/slct.202001836

168. D.A. Ferreira, L.M.D.R.S. Martins, A.R. Fernandes*, M. Martins*, A tale of two ends: repurposing metallic compounds from anti-tumor agents to effective antibacterial, Antibiotics, 2020, 9, 321-334.  - invited paper for the special issue "New Insights into Antibacterial Compounds: From Synthesis and Discovery to Molecular Mechanisms of Action". http://dx.doi.org/10.3390/antibiotics9060321

167. A. Paul*, L.M.D.R.S. Martins*, A. Karmakar, M.L. Kuznetsov, M. F.C. Guedes da Silva*, A.J.L. Pombeiro*, Zn(II)-to-Cu(II) transmetalation in an amide functionalized complex and  catalytic applications in styrene oxidation and nitroaldol coupling, Molecules, 2020, 25, 2644-2657. - invited paper for the special issue "1st CQE Days Meeting: 44 Years Connecting People and Chemistry", https://doi.org/10.3390/molecules25112644

166. D. Ottaviani, V. Van-Dúnem, A.P. Carvalho*, A. Martins*, L.M.D.R.S. Martins,* Eco-friendly cyclohexane oxidation by a v-scorpionate complex immobilized at hierarchical mor zeoliteCatal. Today, 2020, 348, 37-44. https://doi.org/10.1016/j.cattod.2019.09.034

165. A. Paul* L.M.D.R.S. Martins*, A. Karmakar, M.L. Kuznetsov*, A.S. Novikov, M. F.C. Guedes da Silva*, A.J.L. Pombeiro*, Environmentally Benign Benzyl Alcohol Oxidation and C-C Coupling Catalysed by Amide Functionalized 3D Co(II) and Zn(II) Metal Organic Frameworks, J. Cat. 2020, 385. 324?337. https://doi.org/10.1016/j.jcat.2020.03.035

164. E.J.C. Lopes, A.P.C. Ribeiro*, L.M.D.R.S. Martins*, New trends in the conversion of CO2 to cyclic carbonates, Catalysts, 2020, 10, 479-492.- invited paper  https://doi.org/10.3390/catal10050479

163. M. Sutradhar*, T.R. Barman, A.J.L. Pombeiro, L.M.D.R.S. Martins*, Aroylhydrazone Schiff base derived Cu(II) and V(V) complexes:  efficient catalysts towards neat microwave-assisted oxidation of alcohols, Int. J. Mol. Sci., 2020, 20, 2832-2846 - invited paper for the special issue "Oligonuclear Metal Complexes" http://dx.doi.org/10.3390/ijms21082832

162. A. Karmakar*, L.M.D.R.S. Martins*, Y. Yahorava, M.F.C.G. Silva, A.J.L. Pombeiro*, Synthesis, structures, electrochemistry and catalytic activity towards cyclohexanol oxidation of mono-, di- and poly-nuclear iron(III) complexes with 3-amino-2-pyrazinecarboxylate, Appl. Sci., 2020, 10, 2692-2710 - invited paper for the special issue "Advances on Coordination Chemistry with Nitrogen Ligands and Its Applications" http://dx.doi.org/10.3390/app10082692

161. L.M.D.R.S. Martins, Special Issue: Coordination Chemistry and CatalysisCatalysts., 2020, 10, 419-420 - Editorial http://dx.doi.org/10.3390/catal10040419

160. O. Cuzan-Munteanu, D. Sirbu, M. Giorgi, S. Shova, E.A. Gibson, M. Réglier, M. Orio, L.M.D.R.S. Martins, A.C. Benniston, Neutral Lipophilic Palladium(II) Complexes and their Applications in Electrocatalytic Hydrogen Production and C-C Coupling ReactionsEurJIC2020, 813-822. http://dx.doi.org/10.1002/ejic.201901283

159. T.F.S. Silva, L.M.D.R.S. Martins, Recent Advances in Copper Catalyzed Alcohol Oxidation in Homogeneous Medium, Molecules, 2020, 25, 748-762 - invited paper http://dx.doi.org/10.3390/molecules25030748

158. T.A.G. Duarte, I. Favier, C. Pradel, L.M.D.R.S. Martins, A.P. Carvalho, D. Pla; M. Gomez, Tetraalkylammonium functionalized hydrochars as efficient supports for palladium nanocatalysts, ChemCatChem., 2020, 12, 1-10. http://dx.doi.org/10.1002/cctc.201902305

157. E. Pakrieva, A.P.C. Ribeiro, E. Kolobova, L.M.D.R.S. Martins, S.A.C. Carabineiro, D. German, D. Pichugina, C. Jiang, A.J.L. Pombeiro, N. Bogdanchikova, V.C. Corberán, A. Pestryakov, Supported Gold Nanoparticles as Catalysts in Peroxidative and Aerobic Oxidation of 1-Phenylethanol under Mild Conditions, Nanomaterials, 2020, 10, 151-157. http://dx.doi.org/10.3390/nano10010151

156. M.A. Andrade, L.M.D.R.S. Martins,* Sustainability in catalytic cyclohexane oxidation: the contribution of porous support materialsCatalysts, 2020, 10, 2-33 -  invited paper http://dx.doi.org/10.3390/catal10010002

M. Sutradhar,* T.R. Barman, A.J.L. Pombeiro, L.M.D.R.S. Martins*, Cu(II) and Fe(III) complexes derived from N-acetylpyrazine-2-carbohydrazide as efficient catalysts towards solvent-free microwave assisted oxidation of alcoholsCatalysts, 2019,9, 1053-1067. -  invited paper for the special issue "Coordination Chemistry and Catalysis" https://doi.org/10.3390/catal9121053

154. L.M.D.R.S. Martins, The role of carbon materials as supports for transition metal-based catalysts, Boletin del Grupo Espanol del Carbon, 2019, 54, 27-32. - invited paper. ISSN 2172 - 6094 http://www.gecarbon.org/Boletines/Boletin/BoletinGEC_054.pdf

153. P. Pedrosa, M.L. Corvo, M.F. Silva, P. Martins, M.C. Carvalheiro, P. Costa, C. Martins, L.M.D.R.S. Martins, P.V. Baptista, A.R. Fernandes, Targeting cancer resistance via multifunctional gold-nanoparticles,  Int. J. Mol. Sci., 2019, 20, 5510-5516. - invited paper for the special issue "Translating Gold Nanoparticles to Diagnostics and Therapeutics 2.0" https://doi.org/10.3390/ijms20215510
152. A. Dobrov, D. Darvasiová, M. Zalibera, L. Buinský, I. Pu?kárová, P. Rapta, L.M.D.R.S. Martins,* A.J.L. Pombeiro, V.B. Arion,* Nickel(II) complexes with redox noninnocent octaazamacrocycles as catalysts in oxidation reactions, Inorg. Chem. 2019, 58, 11133?11145 http://dx.doi.org/10.1021/acs.inorgchem.9b01700

151. J. Almeida, C. Roma-Rodrigues, P.V. Baptista, A.G. Mahmoud, M.F.C. Guedes da Silva, A.J.L. Pombeiro, L.M.D.R.S. Martins, A.R. Fernandes, Structural characterization and biological properties of silver(I) tris(pyrazolyl)methane sulfonateJ. Inorg. Biochem. 2019, 199, 110789-110802.  https://doi.org/10.1016/j.jinorgbio.2019.110789

150. L.M.D.R.S. Martins, C-scorpionate complexes: ever young catalytic toolsCoord. Chem. Rev. 2019, 396 89-102. https://doi.org/10.1016/j.ccr.2019.06.009

149. B.V. Zakharchenko, D.M. Khomenko, R.O. Doroshchuk, I.V. Raspertova, V.S. Starova, V.V. Trachevsky, S. Shova, O.V. Severynovska, L.M.D.R.S. Martins,* A.J.L. Pombeiro, V.B. Arion, R.D. Lampeka,* New palladium(II) complexes with 3-(2-pyridyl)-5-alkyl-1,2,4-triazole ligands as recyclable C-C coupling catalystsNew J. Chem., 2019, 43, 10973 ? 10984. 

148. M. Sutradhar,* T.R. Barman, A.J.L. Pombeiro, L.M.D.R.S. Martins*, Ni(II)-Aroylhydrazone Complexes as Catalyst Precursors Towards Efficient Solvent-Free Nitroaldol Condensation Reaction, Catalysts, 2019, 9, 554-566. - featured paper http://dx.doi.org/10.3390/catal9060554

147. A.G. Mahmoud, L.M.D.R.S. Martins*, M.F.C. Guedes da Silva, A.J.L. Pombeiro, Hydrosoluble complexes bearing tris(pyrazolyl)methane sulfonate ligand: synthesis, characterization and catalytic activity for Henry reaction, Catalysts, 2019, 9, 611-624.

146. I.A.S. Matias, A.P.C. Ribeiro,* L.M.D.R.S. Martins,* New C-scorpionate nickel(II) catalyst for Heck C-C coupling under unconventional conditionsJ. Organomet. Chem., 2019, 896, 32-37. invited paper for the special issue  "Synthesis and Applications of Organometallic Compounds". http//dx.doi.org/10.1016/j.jorganchem.2019.05.019

145. M. Sutradhar,* L.M.D.R.S. Martins,* T.R. Barman, M.L. Kuznetsov,* M.F.C. Guedes da Silva , A.J.L. Pombeiro,* Vanadium complexes of different nuclearities in the catalytic oxidation of cyclohexane and cyclohexanol - An experimental and theoretical investigationNew J. Chem., 2019, 43, 17557-17570, http://dx.doi.org/10.1039/c9nj00348g

144. Z. Ma, Q. Wang, E.C.B.A. Alegria, M.F.C.G. Silva, L.M.D.R.S. Martins, J. Telo, I. Correia, A.J.L. Pombeiro, Synthesis and Structure of Copper Complexes of a N6O4 Macrocyclic Ligand and Catalytic Application in Alcohol Oxidation, Catalysts, 2019, 9, 424-447. - invited paper for the special issue "Recent Advances in Homogeneous Catalysis" http://dx.doi.org/10.3390/catal9050424

143. G.B. Shul'pin, L.M.D.R.S. Martins, R. Adams, Preface "Synthesis and Applications of Organometallic Compounds"J. Organomet. Chem., 2019, 891, 85. - Editorial https://doi.org/10.1016/j.jorganchem.2019.04.013

142. G.B. Shul?pin, L.M.D.R.S. Martins, R. Adams, Biosketch ? Professor Armando J. L. Pombeiro: "Synthesis and Applications of Organometallic Compounds"J. Organomet. Chem., 2019, 891, 86-87- Editorial  https://doi.org/10.1016/j.jorganchem.2019.04.005
141. G.B. Shulpin, L.M.D.R.S. Martins, K.T. Mahmudov, Biographical sketch of Professor Armando J. L. Pombeiro, Coord. Chem. Rev. 2019, 380, 601-603. - Editorial  https://doi.org/10.1016/j.ccr.2018.09.007
140. G.B. Shulpin, D.C. Crans, L.M.D.R.S. Martins, K.T. Mahmudov, Preface of Coordination Compounds and Catalysis, Coord. Chem. Rev. 2019, 380, 600 - Editorial https://doi.org/10.1016/j.ccr.2018.09.006

139. N.M.R. Martins, A.J.L. Pombeiro, L. M.D.R.S. Martins*, Green oxidation of cyclohexane catalyzed by recyclable magnetic transition-metal silica coated nanoparticles, Catal. Comm., 2019, 125, 15-20. http://dx.doi.org/10.1016/j.catcom.2019.03.015

138. I.A.S. Matias, A.P.C. Ribeiro, E.C.B.A. Alegria, A.J.L. Pombeiro, L.M.D.R.S. Martins*, C-scorpionate iron(II) complexes as highly selective catalysts for the hydrocarboxylation of cyclohexane,  Inorg. Chim. Acta., 2019, 489, 269-274 http://dx.doi.org/10.1016/j.ica.2019.02.035

137. A.S. Smirnov, L.M.D.R.S. Martins,* D.N. Nikolaev, R.A. Manzhos, V.V. Gurzhiy, A.G. Krivenko, A.V. Belyakov, P.B. Davidovich,* Structure and Catalytic Properties of Novel Copper Isatin Schiff BaseNew J. Chem., 2019, 43, 188-198. http://dx.doi.org/10.1039/C8NJ02718H

136. M. Sutradhar,* T.R. Barman, A.J.L. Pombeiro, L.M.D.R.S. Martins,*  Catalytic activity of polynuclear vs. dinuclear aroylhydrazone Cu(II) complexes in microwave-assisted oxidation of neat aliphatic and aromatic hydrocarbonsMolecules, 2019, 24, 47-58 - invited paper for the special issue "Metal Complexes of Biological Ligands" http://dx.doi.org/10.3390/molecules24010047

135. M.A. Andrade, L.M.D.R.S. Martins*, Novel chemotherapeutic agents - the contribution of scorpionates, Current Medicinal Chemistry, 2019, 26, 1-13 - invited review for the thematic issue "Recent developments in anti-cancer drug research"

134. I.A.S. Matias, A.P.C. Ribeiro, R.P. Oliveira-Silva, D.M.F. Prazeres, L.M.D.R.S. Martins*, Gold nanotriangles as selective catalysts for cyclohexanol and cyclohexanone production, Appl. Sci., 2018, 8, 2655-2666. - invited paper for the special issue "Gold Nanoparticles for Catalytic Applications" http://dx.doi.org/10.3390/app8122655

133. L.M.D.R.S. Martins*, R. Wanke, T.F.S. Silva, A.J.L. Pombeiro, P. Servin, R. Laurent A.-M. Caminade, Novel methinic functionalized and dendritic C-scorpionates, Molecules, 2018, 23, 3066-3082 - invited paper for the special issue "Scorpionate Ligands: Ever-Young Chemistry Tools? http://dx.doi.org/10.3390/molecules23123066 Front Cover article of the Issue https://www.mdpi.com/1420-3049/23/12

132. A.G. Mahmoud, L.M.D.R.S. Martins,* M.F.C. Guedes da Silva,* A.J.L. Pombeiro, Copper complexes bearing C-scorpionate ligands: synthesis, characterization and catalytic activity for azide-alkyne cycloaddition in aqueous medium, Inorg. Chim. Acta, 2018, 483, 371-378. https://doi.org/10.1016/j.ica.2018.08.052

131. P. Pedrosa, R. Mendes, R. Cabral, L.M.D.R.S. Martins; P.V. Baptista, A.R. Fernandes, Combination of chemotherapy and Au-nanoparticle photothermy in the visible to tackle drug resistance in cancer cells, Scientific Reports, 2018, 8, 11429-11436 http://dx.doi.org/10.1038/s41598-018-29870-0

130. N.M.R. Martins, A.J.L. Pombeiro, L.M.D.R.S. Martins*, Novel green methodology for the selective oxidation of styrene catalysed by magnetic metal-transition ferrite nanoparticles, Cat. Comm., 2018, 116, 10-15. http://dx.doi.org/10.1016/j.catcom.2018.08.002

129. V. Van-Dúnem, A.P. Carvalho*, L.M.D.R.S. Martins*, A. Martins*, Improved cyclohexane oxidation catalyzed by a heterogenised iron(II) complex on hierarchical Y zeolite through surfactant mediated technology, ChemCatChem, 2018, 10, 4058?4066 - invited paper for the special issue "Portuguese Conference on Catalysis". https://doi.org/10.1002/cctc.201800921

128. T.A.G. Duarte, A.P. Carvalho*, L.M.D.R.S. Martins*, Ultra-fast and selective oxidation of styrene to benzaldehyde catalyzed by a C-scorpionate Cu(II) complex, Catal. Sci. & Tech., 2018,8, 2285-2288.  https://doi.org/10.1039/C8CY00136G  Back Cover article of the Issue https://doi.org/10.1039/C8CY90036A

127. A.P.C. Ribeiro, L.M.D.R.S. Martins*, S.A.C. Carabineiro*, J.G. Buijnsters, J.L. Figueiredo, A.J.L. Pombeiro, Heterogenised C-scorpionate iron(II) complex on nanostructured carbon materials as catalysts for microwave-assisted oxidation reactions,  ChemCatChem, 2018, 10, 1821-1828. - invited paper for the special issue "Supported Molecular Catalysts" https://doi.org/10.1002/cctc.201702031. Inside Cover article of the Issue p. 1659 https://doi.org/10.1002/cctc.201800568

126.  S.A.C. Carabineiro*, L.M.D.R.S. Martins*, A.J.L. Pombeiro, J.L. Figueiredo, Commercial gold(I) and gold(III) compounds supported on carbon materials as greener catalysts for the oxidation of alkanes and alcohols, ChemCatChem, 2018, 10, 1804-1813. invited paper for the special issue "Supported Molecular Catalysts"  https://doi.org/10.1002/cctc.201701886. Front Cover article of the Issue https://doi.org/10.1002/cctc.201800566. Cover Profile p. 1661-1662 https://doi.org/10.1002/cctc.201800575.

125. G.S. Mishra, E.C.B.A. Alegria*, A.J.L. Pombeiro L.M.D.R.S. Martins*, Highly Active and Selective Supported Rhenium Catalysts for Aerobic Oxidation of n-Hexane and n-Heptane Catalysts, 2018, 8, 114-129.- invited paper for the special issue "New Trends in Scorpionate Catalysts". https://doi.org/10.3390/catal8030114

124. A.P.C. Ribeiro*, I.A.S. Matias, E.C.B.A. Alegria, A.M. Ferraria, A.M.B. Rego, A.J.L. Pombeiro, L.M.D.R.S. Martins*, New trendy magnetic C-scorpionate iron catalyst and its performance towards cyclohexane oxidation, Catalysts, 2018, 8, 69-79.- invited paper for the special issue "New Trends in Scorpionate Catalysts". https://doi.org/10.3390/catal8020069 Featured paper

123. R. Jlassi, A.P. C. Ribeiro, G.A.O. Tiago, J. Wang, M.S. Krawczyk, L.M.D.R.S. Martins, H. Naïli, A.J..L. Pombeiro, W. Rekik, Elementary and efficient catalyst process for the Knoevenagel condensation of araldehydes with arylmethylidene malononitrile, Inorg. Chim. Acta, 2018, 471, 76-81. https://doi.org/10.1016/j.ica.2017.10.028

122. N.M.R. Martins, L.M.D.R.S. Martins,* C.O. Amorim, V.S. Amaral, A.J.L. Pombeiro, First-row-transition ion metals(II)-EDTA functionalized magnetic nanoparticles as catalysts for solvent-free microwave-induced oxidation of alcohols, Catalysts, 2017, 335-354.- invited paper https://doi.org/10.3390/catal7110335  Front Cover article of the Issue http://www.mdpi.com/2073-4344/7/11

121. M. Zaltariov, V. Vieru, M. Zalibera, M. Cazacu, N.M.R. Martins, L.M.D.R.S. Martins,* P. Rapta, G. Novitchi, S. Shova, A.J.L. Pombeiro, V.B. Arion,* A new bis(µ-chlorido) bridged cobalt(II) complex with silyl-containing Schiff-base as catalyst precursor in solvent-free oxidation of cyclohexane, EurJIC, 2017,4324?4332. http://doi.org/10.1002/ejic.201700875

120. A.P.C. Ribeiro, L.M.D.R.S. Martins*, A.J.L. Pombeiro, Carbon dioxide-to-methanol single-pot conversion using a C-scorpionate iron(II) catalyst, Green Chem. 2017, 19, 4801-4962. - part of the themed collection: International Symposium on Green Chemistry 2017. This article is part of themed collection: 2017 Green Chemistry Hot Articles
 http://dx.doi.org/10.1039/c7gc01993a Front Cover article of the Issue 

119. A.P.C. Ribeiro, L.M.D.R.S. Martins*, S.A.C. Carabineiro*, J.L. Figueiredo, A.J.L. Pombeiro, Gold nanoparticles deposited on surface modified carbon materials as reusable catalysts for hydrocarboxylation of cyclohexane, Appl. Catal. A: Gen., 2017, 547, 124-131.  http://dx.doi.org/10.1016/j.apcata.2017.08.028  Perspective

118. A.P.C. Ribeiro, LM.D.R.S. Martins*, E.C.B.A. Alegria, I.A.S. Matias, T.A.G. Duarte, A.J.L. Pombeiro, Catalytic performance of Fe(II)-scorpionate complexes towards cyclohexane oxidation in organic, ionic liquid and/or supercritical CO2 media: a comparative study, Catalysts, 2017, 7, 230 - invited paper for the special issue "Catalysis in Innovative Solvents".  http://doi.org/10.3390/catal7080230

117. N.M.R. Martins, L.M.D.R.S. Martins,* C.O. Amorim, V.S. Amaral, A.J.L. Pombeiro, Solvent-free microwave-induced oxidation of alcohols catalysed by ferrite magnetic nanoparticles, Catalysts, 2017,7, 222-239 - invited paper for the special issue "Magnetic Nanocatalysts".  http://doi.org/10.3390/catal7070222

116. R. Galassi,* O.C. Simon, A. Burini, G. Tosi, C. Conti, C. Graiff, N.M.R. Martins, M.F.C. Guedes da Silva, A.J.L. Pombeiro,  L.M.D.R.S. Martins,* Copper(I) and copper(II) metallacycles as catalysts for microwave assisted selective oxidation of cyclohexane, Polyhedron. 2017, 134, 143-152. http://doi.org/10.1016/j.poly.2017.06.020

115. L.M.D.R.S. Martins, C-homoscorpionate oxidation catalysts - electrochemical and catalytic activity, Catalysts, 2017, 7, 12 - invited paper for the special issue "New Trends in Scorpionate Catalysts"  http://dx.doi.org/10.3390/catal7010012.

114. L.M.D.R.S. Martins,* A.J.L. Pombeiro, C-scorpionate rhenium complexes and their application as catalysts in Baeyer-Villiger oxidation of ketones, Inorg. Chim. Acta, 2017, 455, 390-397 - invited paper for the special issue "Metal Systems for a Sustainable Chemistry". http://dx.doi.org/10.1016/j.ica.2016.06.018

113. J. Wang, L.M.D.R.S. Martins, A.P.C. Ribeiro, S.A.C. Carabineiro, J.L. Figueiredo, A.J.L. Pombeiro, Supported C-scorpionate vanadium(IV) complexes as reusable catalysts for xylene oxidation, Chem. Asian J., 2017, 12, 1915-1919 - invited paper for the special issue "Vanadium virtual issue"  http://dx.doi.org/10.1002/asia.201700499 Cover article of the Issue http://dx.doi.org/10.1002/asia.201700839.

112. M. Saha, K.M. Vyas, L.M.D.R.S. Martins,* N.M.R. Martins, A.J.L. Pombeiro, S.M. Mobin, D. Bhattacherjee, K.P. Bhabak,c S. Mukhopadhyay,* Copper(II) tetrazolato complexes: role in oxidation catalysis and protein binding, Polyhedron, 2017, 132, 53-63 http://dx.doi.org/10.1016/j.poly.2017.04.016

111. N.M.R. Martins, S. Anbu, Kamran T. Mahmudov, R. Ravishankaran, M.F.C. Guedes da Silva, L.M.D.R.S. Martins, A.A. Karande, A.J.L. Pombeiro, DNA, BSA binding and cytotoxic properties of copper(II) and iron(III) complexes with arylhydrazone of ethyl 2-cyanoacetate or formazan ligands, New J. Chem., 2017, 2017, 41, 4076-4086. http://dx.doi.org/10.1039/c7nj00420f

110. L.M.D.R.S. Martins,* A.P.C. Ribeiro, A.J.L. Pombeiro, Highly Selective Cyclohexane Oxidation Catalyzed by Ferrocene in Ionic Liquid Medium, Lett. Org. Chem, 2017, 14, 571-574 - invited paper. Editor-in-Chief's Choice 

109. A.P.C. Ribeiro, L.M.D.R.S. Martins,* S.A.C. Carabineiro,* J.L. Figueiredo, A.J.L. Pombeiro, Gold nanoparticles deposited on surface modified carbon xerogels as reusable catalysts for cyclohexane C-H activation towards CO and water, Molecules, 2017, 22, 603. - invited paper to the special issue "Reactions of Hydrocarbons and other C-H Compounds" http://dx.doi.org/10.3390/molecules22040603

108. T.F.S. Silva*, A.J. Silvestre,* B.G.M. Rocha, M.R. Nunes, O.C. Monteiro L.M.D.R.S. Martins,* Enhancing alkane oxidation using Co-doped SnO2 nanoparticles as catalysts, Catal. Comm. 2017, 96, 19-22. http://dx.doi.org/10.1016/j.catcom.2017.03.012

107. A.P.C. Ribeiro, L.M.D.R.S. Martins,* A.J.L. Pombeiro, N2O-free single-pot conversion of cyclohexane to adipic acid catalysed by an iron(II) scorpionate complex, Green Chem. 2017, 19, 1499 -1501. http://dx.doi.org/10.1039/C6GC03208G.  This article is part of themed collection: 2017 Green Chemistry Hot Articles

106. L.M.D.R.S. Martins*, S.A.C. Carabineiro*, J. Wang, B.G.M. Rocha, F.J. Maldonado-Hódar, A.J.L. Pombeiro, Supported gold nanoparticles as reusable catalysts for oxidation reactions of industrial significance, ChemCatChem, 2017,9, 1211-1221.. http://dx.doi.org/10.1002/cctc.201601442 Inside Back Cover article of the Issue   http://onlinelibrary.wiley.com/doi/10.1002/cctc.201700465/full

105. S. Hazra,* L.M.D.R.S. Martins,*M. F.C. Guedes da Silva, A. J. L. Pombeiro, Sulfonated Schiff Base Dimeric and Polymeric Copper(II) Complexes: Temperature Dependent Synthesis, Crystal Structure and Catalytic Alcohol Oxidation Studies, Inorg. Chim. Acta, 2017,455, 549-556 - invited paper to the special issue "Metal Systems for a Sustainable Chemistry" http://dx.doi.org/10.1016/j.ica.2016.05.052

104. A.R. Fernandes,* J. Jesus, P. Martins, S. Figueiredo, D. Rosa, L.M.D.R.S. Martins, M.L. Corvo, M.C. Carvalheiro, P.M. Costa, P.V. Baptista,* Multifunctional gold-nanoparticles: A nanovectorization tool for the targeted delivery of novel chemotherapeutic agents, J. Control. Release, 2017, 245, 52-61. http://dx.doi.org/10.1016/j.jconrel.2016.11.021

103. L.R. Raposo, C. Roma-Rodrigues, J. Jesus, L.M.D.R.S. Martins, A.J.L. Pombeiro, P.V. Baptista A.R. Fernandes, Targeting canine mammary tumors via gold nanoparticles functionalized with promising Co(II) and Zn(II) compounds, Vet. Comp. Onc., 2017, 15, 1537-1542.  http://dx.doi.org/10.1111/vco.12298

102. M. Mendes, A.P.C. Ribeiro,* E.C.B.A. Alegria,* L.M.D.R.S. Martins,* Armando J.L. Pombeiro, Liquid phase oxidation of xylenes catalyzed by the tripodal C-scorpionate iron(II) complex [FeCl2{?3-HC(pz)3}], Polyhedron, 2017, 125, 151-155. - invited paper to the special issue "Tridentate and Tetradentate Tripodal Ligands"  http://dx.doi.org/10.1016/j.poly.2016.10.037

101. A.P.C. Ribeiro, L.M.D.R.S. Martins,* M.L. Kuznetsov, A.J.L. Pombeiro, Tuning cyclohexane oxidation: combination of microwave irradiation and ionic liquid with the C-scorpionate [FeCl2(Tpm)] catalyst, Organomet., 2017, 36, pp 192?198. - invited paper for the special issue "Hydrocarbon Chemistry: Activation and Beyond".  http://dx.doi.org/10.1021/acs.organomet.6b00620

100. L.M.D.R.S. Martins,* A.J.L. Pombeiro, Water-soluble C-scorpionate complexes: catalytic and biological applications, Eur. J. Inorg. Chem., 2016, 2236-2252 - invited paper to EurJIC's cluster issue on "Scorpionate ligands as tripodal platform for surface-mounted molecular gears and motors". http://dx.doi.org/10.1002/ejic.201600053 Back cover article of the Cluster Issue http://onlinelibrary.wiley.com/doi/10.1002/ejic.201670154/full

99. N.M.R. Martins, K.T. Mahmudov,* M.F.C. Guedes da Silva,* L.M.D.R.S. Martins,* A.J.L. Pombeiro*, Copper(II) and iron(III) complexes with arylhydrazone of ethyl 2-cyanoacetate or formazan ligands: E/Z isomerization assisted by cooperative coordination and ionic interaction, catalysts for oxidation of alcohols, New J. Chem., 2016,40, 10071-10083. http://dx.doi.org/10.1039/C6NJ02161A

98. E.C.B.A. Alegria, M.F.C. Guedes da Silva, M.L. Kusznetov, L.M.D.R.S. Martins, A. J.L. Pombeiro, Mono-alkylation of cyanoimide at a molybdenum(IV) diphosphinic center by alkyl halides - synthesis, cathodically induced isomerization and theoretical studies, Electrochim. Acta, 2016, 218, 252-262 http://dx.doi.org/10.1016/j.electacta.2016.09.120

97. N.M.R. Martins, K.T. Mahmudov,* M.F.C. Guedes da Silva,* L.M.D.R.S. Martins,* F.I. Guseinov, A.J.L. Pombeiro*, 1D Zn(II) coordination polymer derived from arylhydrazone of 5,5-dimethylcyclohexane-1,3-dione as a pre-catalyst for the Henry reaction, Cat. Com., 2016, 87, 49?52. http://dx.doi.org/10.1016/j.catcom.2016.08.039.

96. D. Dragancea, N. Talmaci, S. Shova, G. Novitchi, D. Darvasiova, P. Rapta,* M. Breza, M. Galanski, J. Kozisek, N.M.R. Martins L. M.D.R.S. Martins,* A.J.L. Pombeiro,* V.B. Arion,* Vanadium(V) complexes with substituted 1,5-bis(2-hydroxybenzaldehyde)carbohydrazones and their use as catalyst precursors in oxidation of cyclohexane, Inorg. Chem., 2016, 55, 9187-9203. http://dx.doi.org/10.1021/acs.inorgchem.6b01011

95. L.M.D.R.S. Martins,* S. Hazra,* M.F..C. Guedes da Silva,  A.J.L. Pombeiro, A Sulfonated Schiff Base Dimethyltin(IV) Coordination Polymer as a Catalyst for Ultrasound- or Microwave-Assisted Baeyer-Villiger Oxidation, RSC Adv., 2016, 6, 78225-78233. http://dx.doi.org/10.1039/C6RA14689A

94. A. Tabacaru, N. Xhaferaj, L.M.D.R.S. Martins,* E.C.B.A. Alegria, R.S. Chay, C. Giacobbe, K.V. Domasevitch, A.J.L. Pombeiro,* S. Galli,* C. Pettinari,* Metal Azolate/Carboxylate Frameworks as Catalysts in Oxidative and C-C Coupling Reactions, Inorg. Chem., 2016, 55, 5804-5817. http://dx.doi.org/10.1021/acs.inorgchem.5b02997

93. M. Sutradhar*, L.M.D.R.S. Martins*, S.A.C. Carabineiro*, M.F.C. Guedes da Silva*, J.G. Buijnsters, J.L. Figueiredo, A.J.L. Pombeiro, Oxidovanadium(V) complexes anchored on carbon materials as catalysts for the oxidation of 1-phenylethanol, ChemCatChem, 2016, 8, 2254-2266.  http://dx.doi.org/10.1002/cctc.201600316

92. M. Sutradhar, E.C.B.A. Alegria, M.F.C. Guedes da Silva, L.M.D.R.S. Martins, A.J.L. Pombeiro, Aroylhydrazone Cu(II) complexes in keto form: structural characterization and catalytic activity towards cyclohexane oxidation, Molecules, 2016, 21, 425, - invited paper to the special issue "Coinage Metal (Copper, Silver, and Gold) Catalysis".  http://dx.doi.org/10.3390/molecules21040425

91. L.M.D.R.S. Martins,* A.P. C. Ribeiro, S.A.C. Carabineiro, J.L. Figueiredo, A.J.L. Pombeiro, Highly efficient and reusable CNT supported iron(II) catalyst for microwave assisted alcohol oxidation, Dalton Trans., 2016, 45, 6816 ? 6819 http://dx.doi.org/10.1039/C6DT00514D

90. A.P.C. Ribeiro, Y.Y. Karabach,* L.M.D.R.S. Martins,* A.G. Mahmoud, M.F.C. Guedes da Silva, A.J.L. Pombeiro,* Nickel(II)-2-amino-4-alkoxy-1,3,5-triazapentadienato complexes as catalysts for Heck and Henry reactions, RSC Adv., 2016, 6, 29159-29163. http://dx.doi.org/10.1039/C6RA02989B

89. A. Karmakar,* L.M.D.R.S. Martins,* S. Hazra, M.F.C. Guedes da Silva, A.J.L. Pombeiro,* Metal?organic frameworks with pyridyl-based isophthalic acid and their catalytic applications in microwave assisted peroxidative oxidation of alcohols and Henry reaction, Cryst. Growth Des., 2016, 16, 1837-1849, http://dx.doi.org/10.1021/acs.cgd.5b01178

88. C.A. Montoya, C.F. Gómez, A.B. Paninho, A.V.M. Nunes, K.T. Mahmudov, V. Najdanovic-Visak, L.M.D.R.S. Martins, M.F.C. Guedes da Silva, M. Nunes da Ponte, A.J.L. Pombeiro, Cyclic carbonate synthesis from CO2 and epoxides using zinc(II) complexes of arylhydrazones of ?-diketones, J. Catal. 2016, 335, 135-140.  http://dx..doi.org/10.1016/j.jcat.2015.12.027

87. T.F.S. Silva,* B.G.M. Rocha, M.F.C. Guedes da Silva, L.M.D.R.S. Martins,* A.J.L. Pombeiro,* VIV, FeII, NiII and CuII complexes bearing 2,2,2-tris(pyrazol-1-yl)ethyl methanesulfonate: application as catalysts for the cyclooctane oxidation, New J. Chem., 2016, 40, 528-537. http://dx.doi.org/10.1039/C5NJ01865J

86. M.N. Kopylovich, A.P.C. Ribeiro, E.C.B.A. Alegria, N.M.R. Martins, L.M.D.R.S. Martins, A.J.L. Pombeiro, Catalytic oxidation of alcohols: recent advances, Adv. Organomet. Chem., 2015, 63, Ch. 3, 91-174 - invited paper.  http://dx.doi.org/10.1016/bs.adomc.2015.02.004

85. M. Sutradhar, L.M.D.R.S. Martins, M.F.C. Guedes da Silva, A.J.L. Pombeiro, Vanadium complexes: Recent progress in oxidation catalysis, Coord. Chem. Rev., 2015,301-302, 200-239 - invited paper for the special issue "The Ninth International Symposium on the Chemistry and Biological Chemistry of Vanadium". http://dx.doi.org/10.1016/j.ccr.2015.01.020 

84. L.M.D.R.S. Martins,* R. Nasani, M. Saha, S.M. Mobin, S. Mukhopadhyay,  A.J.L. Pombeiro, Greener selective cycloalkane oxidation with hydrogen peroxide catalyzed by copper-5-(4-pyridyl)tetrazolate metal-organic frameworks, Molecules, 2015, 20, 19203-19220 - invited paper for the special issue "Metal Mediated Activation of Small Molecules" http://dx.doi.org/10.3390/molecules201019203

83. S. Hazra,* L.M.D.R.S. Martins,* M.F.C. Guedes da Silva, A.J.L. Pombeiro, Sulfonated Schiff Base Copper(II) Complexes as Efficient and Selective Catalysts in Alcohol Oxidation: Syntheses and Crystal Structures, RSC Adv., 2015, 5, 90079-90088. http://dx.doi.org/10.1039/C5RA19498A

82. J. Palmucci, K.T. Mahmudov,* M.F.C. Guedes da Silva, L.M.D.R.S. Martins,* F. Marchetti, C. Pettinari, A.J.L. Pombeiro, Arylhydrazones of Barbituric Acid: synthesis, coordination ability and catalytic activity of their CoII, CoII/III and CuII complexes toward peroxidative oxidation of alkanes, RSC Adv., 2015, 5, 84142-84152. http://dx.doi.org/10.1039/C5RA14078A

81. E.C.B.A. Alegria,* S. Anbu, L.M.D.R.S. Martins, A.J.L. Pombeiro, Electrochemical Properties of Robson type macrocyclic dicopper(II) complexes, Port. Electrochim. Acta, 2015, 33, 201-207. http://dx.doi.org/10.4152/pea.201504201

80. A. Karmakar,* L.M.D.R.S. Martins,* M.F.C. Guedes da Silva, S. Hazra, A.J.L. Pombeiro, Solvent-free Microwave-assisted Peroxidative Oxidation of Alcohols Catalyzed by Iron(III)-TEMPO Catalytic Systems, Catal. Lett., 2015, 1-11. http://dx.doi.org/10.1007/s10562-015-1616-2

79. M. Sutradhar,* L.M.D.R.S. Martins,* M.F.C. Guedes da Silva, C.-M. Liu, A.J.L. Pombeiro, Trinuclear Cu(II) structural isomers:  coordination, magnetism, electrochemistry and catalytic activity toward oxidation of alkanes, Eur. J. Inorg. Chem., 2015, 3959-3969.. http://dx.doi.org/10.1002/ejic.201500440

78. A.P.C. Ribeiro, L.M.D.R.S. Martins, S. Hazra, A.J.L. Pombeiro, Catalytic Oxidation of Cyclohexane with Hydrogen Peroxide and a Tetracopper(II) Complex in an Ionic Liquid, C. R. Chim., 2015, 18, 758-765. http://dx.doi.org/10.1016/j.crci.2015.03.018 - the most cited paper in 2015.

77. I. Timokhin, C. Pettinari, F. Marchetti, R. Pettinari, F. Condello, S. Galli, E.C.B.A. Alegria, L.M.D.R.S. Martins, A.J.L. Pombeiro, Novel Coordination Polymers with (Pyrazolato)-based Tectons: Catalytic Activity in the Peroxidative Oxidation of Alcohols and Cyclohexane, Cryst. Growth Des., 2015, 15, 2303?2317. http://dx.doi.org/10.1021/acs.cgd.5b00083

76. K.T. Mahmudov, M. Sutradhar, L.M.D.R.S. Martins,* M.F.C. Guedes da Silva, A. Ribera, A.V.M. Nunes, S.I. Gahramanova, F. Marchetti, A.J.L. Pombeiro*, MnII and CuII complexes with arylhydrazones of active methylene compounds as effective heterogeneous catalysts for solvent- and additive-free microwave-assisted peroxidative oxidation of alcohols, RCS Adv., 2015, 5, 25979?25987. http://dx.doi.org/10.1039/c5ra02667a

75. M. Sutradhar, L.M.D.R.S. Martins, M.F.C. Guedes da Silva, A.J.L. Pombeiro, Oxido vanadium complexes with tridentate aroylhydrazone as catalyst precursors for solvent-free microwave-assisted oxidation of alcohols, Appl. Cat. A Gen., 2015, 493, 50-57. http://dx.doi.org/10.1016/j.apcata.2015.01.005

74. Z. Ma, H. Shi, X. Deng, M.F.C. Guedes da Silva, L.M.D.R.S. Martins, A. J.L. Pombeiro, Silver coordination polymers with tri- and hexacyanoethyl-functionalized macrocyclic ligands, Dalton Trans., 2015, 44, 1388-1396. http://dx.doi.org/10.1039/C4DT02604G

73. L.M.D.R.S. Martins,* A.J.L. Pombeiro, Tris(pyrazol-1yl)methane metal complexes for catalytic mild oxidative functionalizations of alkanes, alkenes and ketones, Coord. Chem. Rev., 2014, 265, 74-88. http://dx.doi.org/10.1016/j.ccr.2014.01.013

72. L.M.D.R.S. Martins,* C. Pettinari, Fabio Marchetti, E.C.B.A. Alegria, A.J.L. Pombeiro, Electrochemical Properties of (h5-C5Me5)?Rhodium and ?Iridium Complexes Containing Bis(pyrazolyl)alkane Ligands, Port. Electrochim. Acta, 2014, 32, 253-257.  http://dx.doi.org/10.4152/pea.201404253

71. K.T. Mahmudov, M.N. Kopylovich, A. Sabbatini, M.G.B. Drew, L.M.D.R.S. Martins, C. Pettinari, A.J.L. Pombeiro, Cooperative Metal-Ligand Assisted E/Z Isomerisation and Cyano-groups Activation at CuII and CoII Complexes of Arylhydrazones of Active Methylene Nitriles, Inorg. Chem., 2014, 53, 9946?9958. http://dx.doi.org/10.1021/ic501704g

70. B.G.M. Rocha, T.C.O. Mac Leod, M.F.C. Guedes da Silva, K.V. Luzyanin, L.M.D.R.S. Martins, A.J.L. Pombeiro, NiII, CuII and ZnII Complexes with a Sterically Hindered Scorpionate Ligand (TpmsPh) and Catalytic Application in the Diasteroselective Nitroaldol (Henry) Reaction, Dalton Trans., 2014, 43, 15192-15200. http://dx.doi.org/10.1039/c4dt01509f

69. N.Q. Shixaliyev, A.V. Gurbanov, A.M. Maharramov, K.T. Mahmudov, M.N. Kopylovich, L.M.D.R.S. Martins, V.G. Nenajdenko, A.J.L. Pombeiro, Halogen-bonded (2,4-bis(trichloromethyl)-1,3,5-triazapentadienato)-M(III) [M = Mn, Fe, Co] complexes and their catalytic activity in the peroxidative oxidation of 1-phenylethanol to acetophenone, New J. Chem., 2014, 38, 4807-4815. http://dx.doi.org/10.1039/C4NJ00797B

68. R. Nasani, M. Saha, S.M. Mobin, L.M.D.R.S. Martins, A.J.L. Pombeiro, A.M. Kirillov, S. Mukhopadhyay, Copper-organic frameworks assembled from in-situ generated 5-(4-pyridyl)tetrazole building blocks: synthesis, structural features, topological analysis and catalytic oxidation of alcohols, Dalton Trans., 2014, 43, 9944-9954. http://dx.doi.org/10.1039/C4DT00531G

67. J. Sedlacek, L.M.D.R.S. Martins, P. Danek, A.J.L. Pombeiro, B. Cvek, Diethyldithiocarbamate complexes with metals used as food supplements show different effect in cancer cells, J. Appl. Biomed., 2014, 12, 301-308. http://dx.doi.org/10.1016/j.jab.2014.04.002

66. S. Orbisaglia, C. Di Nicola, F. Marchetti, C. Pettinari, R. Pettinari, L.M.D.R.S. Martins, E.C.B.A. Alegria, M.F.C. Guedes da Silva, B.G.M. Rocha, M.L. Kuznetsov, A.J.L. Pombeiro, B.W. Skelton, A.N. Sobolev, A.H. White, Novel (arene)Ru(II) complexes with halogen-substituted bis- and tris-(pyrazol-1-yl)borate ligands, Chem. Eur. J., 2014, 20, 3689-3704.  http://dx.doi.org/10.1002/chem.201304406

65. A. Sabbatini, L.M.D.R.S. Martins,* K.T. Mahmudov, M.N. Kopylovich, M.G.B. Drew, C. Pettinari, A.J.L. Pombeiro,* Microwave-assisted and solvent-free peroxidative oxidation of 1-phenylethanol to acetophenone with a CuII-TEMPO catalytic system Catal. Com., 2014, 48, 69-72.

64. T.F.S. Silva, L.M.D.R.S. Martins, M.F. Guedes da Silva, M.L. Kuznetsov, A.R. Fernandes, A. Silva, S. Santos, C.-J. Pan, J.-F. Lee, B.-J. Hwang, A.J.L. Pombeiro, Cobalt complexes with pyrazole ligands as catalysts for the peroxidative oxidation of cyclohexane. XAS studies and biological applications, Chem. Asian J., 2014, 9, 1132-1143.  http://dx.doi.org/10.1002/asia.201301331

63. D.V. Luís, J. Silva, A.I. Tomaz, R.F.M. Almeida, L.M.D.R.S. Martins, T.F.S. Silva, P.M. Borralho, C.M.P. Rodrigues, A.S. Rodrigues, A.J.L. Pombeiro, A.R. Fernandes, Insights into the mechanisms underlying the anti-proliferative potential of a Co(II) coordination compound bearing 1,10-phenanthroline-5,6-dione: DNA and protein interaction studies, J. Biol. Inorg. Chem., 2014, 787-803. http://dx.doi.org/10.1007/s00775-014-1110-0

62. M. Sutradhar, L.M.D.R.S. Martins, M.F.C. Guedes da Silva, E.C.B.A. Alegria, Cai-Ming Liu, A.J.L. Pombeiro, Dinuclear Mn(II,II) complexes: microwave assisted oxidation of alcohols and studies of magnetic properties, Dalton Trans.,  2014, 43, 3966-3977.  http://dx.doi.org/10.1039/c3dt52774c

61. Z. Ma, L. Wei, E.C.B.A. Alegria, L.M.D.R.S. Martins, M.F.C. Guedes da Silva, A.J.L. Pombeiro, Synthesis and characterization of copper(II) 4?-phenyl-terpyridine compounds and catalytic application for aerobic oxidation of benzylic alcohols, Dalton Trans., 2014, 43, 4048-4058.  http://dx.doi.org/10.1039/c3dt53054j

60. M. Alexandru, M. Cazacu, A. Arvinte, S. Shova, C. Turta, B.C. Simionescu, A. Dobrov, E.C.B.A. Alegria, L.M.D.R.S. Martins, A.J.L. Pombeiro, V.B. Arion, Chlorido-bridged dimanganese(II) complexes of the Schiff base derived from [2+2]condensation of 2,6-diformyl-4-methylphenol and 1,3-bis(3-aminopropyl)tetramethyldisiloxane: Structure, Magnetism, Electrochemical Behaviour and Catalytic Oxidation of Secondary Alcohols, Eur. J. Inorg. Chem., 2014, 120-131 http://dx.doi.org/10.1002/ejic.201300969

59. M. Peixoto de Almeida, L.M.D.R.S. Martins,* S.A.C. Carabineiro,* T. Lauterbach, F. Rominger, A.S.K. Hashmi, A.J.L. Pombeiro, J.L. Figueiredo, Homogeneous and Heterogenised New Gold C-Scorpionate Complexes as Catalysts for Cyclohexane Oxidation, Catal. Sci. Technol., 2013, 3, 3056-3069. http://dx.doi.org/10.1039/C3CY00552F

58. L.M.D.R.S. Martins,* A. Martins, E.C.B.A. Alegria, A.P. Carvalho, A.J.L. Pombeiro, Efficient cyclohexane oxidation with hydrogen peroxide catalysed by a C-scorpionate iron(II) complex immobilized on desilicated MOR zeolite, Appl. Catal. A-Gen., 2013, 464-465, 43-50. http://dx.doi.org/10.1016/j.apcata.2013.05.022

57. S.A.C. Carabineiro,* L.M.D.R.S. Martins,* M. Avalos-Borja, J.G. Buijnsters, A.J.L. Pombeiro, J.L. Figueiredo, Gold Nanoparticles Supported on Carbon Materials for Cyclohexane Oxidation with Hydrogen Peroxide, Appl. Catal. A-Gen.,  2013, 467, 279-290. http://dx.doi.org/10.1016/j.apcata.2013.07.035

56. A. Silva, D. Luís, S. Santos, J. Silva, A.S. Mendo, L. Coito, T.F.S. Silva, M.F.C. Guedes da Silva, L.M.D.R.S. Martins, A.J.L. Pombeiro, P. Borralho, C.M. Rodrigues, G. Cabral, P. Videira, C. Monteiro, A.R. Fernandes, Biological characterization of the antiproliferative potential of Co(II) and Sn(IV) coordination compounds in human cancer cell lines: role of comparative proteomics, Drug Metabol. & Drug Interact. 2013, 28, 167?176. http://dx.doi.org/10.1515/dmdi-2013-0015

55. M.N.M. Milunovic, L.M.D.R.S. Martins, E.C.B.A. Alegria, A.J.L. Pombeiro, R. Krachler, G. Trettenhahn, C. Turta, S. Shova, V.B. Arion, Hexanuclear and Undecanuclear Iron(III) Carboxylates as Catalyst Precursors for Cyclohexane Oxidation, Dalton Trans., 2013, 42, 14388-14401.  http://dx.doi.org/10.1039/c3dt50966d  - cover article of ISSUE 42, number 40, October 2013 Dalton Transactions, ISSN 1477-9226 http://pubs.rsc.org/en/content/articlelanding/2013/dt/c3dt90145a#!divAbstract

54. L.M.D.R.S. Martins,* M. Peixoto de Almeida, S.A.C. Carabineiro,* J.L. Figueiredo, A.J.L. Pombeiro, Heterogenisation of a C-scorpionate Fe(II) complex in carbon materials for cyclohexane oxidation with hydrogen peroxide, ChemCatChem, 2013, 5, 3847?3856. http://dx.doi.org/10.1002/cctc.201300432

53. T.F.S. Silva, P. Smole?ski, L.M.D.R.S. Martins, M.F. Guedes da Silva, A.R. Fernandes, D. Luís, A. Silva, S. Santos, P.M. Borralho, C.M.P. Rodrigues, A.J.L. Pombeiro, Cobalt and zinc compounds bearing 1,10-phenantroline-5,6-dione or 1,3,5-triaza-7-phosphaadamantane derivatives: synthesis, characterization, cytotoxicity and selectivity studies, Eur. J. Inorg. Chem., 2013, 21, 3651-3658. http://dx.doi.org/10.1002/ejic.201300197

52. L.M.D.R.S. Martins,* E.C.B.A. Alegria, P. Smole?ski, M.L. Kuznetsov, A.J.L. Pombeiro, Oxorhenium complexes bearing the water-soluble tris(pyrazol-1-yl)methanesulfonate, 1,3,5-triaza-7-phosphaadamantane or related ligands, as catalysts for the Baeyer-Villiger oxidation of ketones, Inorg. Chem., 2013, 52, 4534-4546. http://dx.doi.org/10.1021/ic400024r

51. X. Shang, T.F.S. Silva, L.M.D.R.S. Martins, Q. Li, M.F.C. Guedes da Silva, M.L. Kuznetsov, A.J.L. Pombeiro, Synthesis, characterization, electrochemical behavior and in vitro protein tyrosine kinase inhibitory activity of the cymene-halogenobenzohydroxamate [Ru(?6-cymene)(BHA)Cl] complexes, J. Organomet. Chem., 2013, 730, 137-143. http://dx.doi.org/10.1016/j.jorganchem.2012.12.013

50. M.N. Kopylovich, M.F.C. Guedes da Silva, L.M.D.R.S. Martins, M.L. Kuznetsov, K.T. Mahmudov, A.J.L. Pombeiro, Synthesis, structure and electrochemical behaviour of Na, MgII, MnII, ZnII, CdII and NiII complexes of 3-(2-carboxyphenylhydrazone)pentane-2,4-dione, Polyhedron, 2013, 50, 374-382.

49. T.F.S. Silva, T.C.O. Mac Leod, L.M.D.R.S. Martins, M.F. Guedes da Silva, M.A. Schiavon, A.J.L. Pombeiro, Pyrazole or tris(pyrazolyl)ethanol oxo-vanadium(IV) complexes as homogeneous or supported catalysts for oxidation of cyclohexane under mild conditions, J. Mol. Cat. A: Chemical, 2013, 367, 52-60. http://dx.doi.org/10.1016/j.molcata.2012.10.024

48. M. Sutradhar, M.V. Kirillova, M.F.C. Guedes da Silva, L.M.D.R.S. Martins, A.J.L. Pombeiro, A Hexanuclear Oxovanadium(IV,V) Complex Bearing N,O-Ligand as a Highly Efficient Alkane Oxidation Catalyst, Inorg. Chem., 2012, 51, 11229?11231. http://dx.doi.org/10.1021/ic3017062 

47. E.C.B. Alegria, L.M.D.R.S. Martins, M.V. Kirillova, A.J.L. Pombeiro, Baeyer-Villiger oxidation of ketones catalyzed by rhenium complexes bearing N- or O-ligands, Appl. Catal. A-Gen., 2012, 443-444, 27-32. http://dx.doi.org/10.1016/j.apcata.2012.07.007

46. E.C.B.A. Alegria, M.F.C. Guedes da Silva, M.L. Kuznetsov, S.M.P.R.M. Cunha, L.M.D.R.S. Martins, A.J.L. Pombeiro, Acylated Cyanoimido-Complexes trans-[Mo(NCN){NCNC(O)R}(dppe)2]Cl and their Reactions with Electrophiles: Chemical, Electrochemical and Theoretical Study, Dalton Trans., 2012, 41, 13876-13890. http://dx.doi.org/10.1039/C2DT30867C

45. T.F.S. Silva, L.M.D.R.S. Martins, M.F. Guedes da Silva, A.R. Fernandes, A. Silva, P.M. Borralho, S. Santos, C.M.P. Rodrigues, A.J.L. Pombeiro, Cobalt complexes bearing scorpionate ligands: synthesis, characterization, cytotoxicity and DNA cleavage, Dalton Trans., 2012, 41, 12888-12897. http://dx.doi.org/10.1039/c2dt11577h

44. B.G.M. Rocha, R. Wanke, M.F.C. Guedes da Silva, K.V. Luzyanin, L.M.D.R.S. Martins, P. Smolénski, A.J.L. Pombeiro, Reactivity of bulky tris(phenylpyrazolyl)methanesulfonate copper(I) complexes towards small unsaturated molecules, J. Organomet. Chem., 2012, 714, 47?52.

43. F. Marchetti, C. Pettinari,* R. Pettinari, A. Cerquetella, L.M.D.R.S. Martins,* M.F. Guedes da Silva, T.F.S. Silva, A.J.L. Pombeiro,* Ru(II) arene complexes bearing tris(pyrazolyl)methanesulfonate capping ligands. Electrochemistry, spectroscopic and X-ray structural characterization, Organometallics, 2011, 30, 6180-6188. http://dx.doi.org/10.1021/om200713v

42. C. Pettinari,* F. Marchetti, A. Cerquetella, R. Pettinari, M. Monari, T.C.O. Mac Leod, L.M.D.R.S. Martins, A.J.L. Pombeiro,* Coordination chemistry of the (?6-cymene)ruthenium(II) fragment with bis-, tris-, and tetrakis(pyrazol-1-yl)borate ligands: synthesis, structural, electrochemical and catalytic diastereoselective nitroaldol reaction studies, Organometallics, 2011, 30, 1616-1626. http://dx.doi.org/10.1021/om101146q

41. C. Pettinari, F. Marchetti, G. Lupidi, L. Quassinti, M. Bramucci, D. Petrelli, L.A. Vitali, M.F.C. Guedes da Silva, L.M.D.R.S. Martins, P. Smole?ski, A.J.L. Pombeiro, Synthesis, Antimicrobial and Antiproliferative Activity of Novel Silver(I) Tris(pyrazolyl)methanesulfonate and 1,3,5-Triaza-7-phosphadamantane Complexes, Inorg. Chem., 2011, 50, 11173-11183. http://dx.doi.org/10.1021/ic201714c

40. M.N. Kopylovich, A.C.C. Nunes, K.T. Mahmudov, M. Haukka, T.C.O. Mac Leod, L.M.D.R.S. Martins, M.L. Kuznetsov, A.J.L. Pombeiro, Complexes of copper(II) with 3-(ortho-substituted phenylhydrazo)pentane-2,4-diones: syntheses, properties and catalytic activity for cyclohexane oxidation, Dalton Trans., 2011, 40, 2822-2836. http://dx.doi.org/10.1039/c0dt01527j

39. T.F.S. Silva, M.F.C.G. Silva, G.S. Mishra, L.M.D.R.S. Martins, A.J.L. Pombeiro, Synthesis and structural characterization of iron complexes with 2,2,2-tris(1-pyrazolyl)ethanol ligands: application in the peroxidative oxidation of cyclohexane under mild conditions, J. Organomet. Chem., 2011, 696, 1310-1318. http://dx.doi.org/10.1016/j.jorganchem.2010.12.036

38. M.N. Kopylovich, K.T. Mahmudov, M.F.C.G. Silva, L.M.D.R.S. Martins, M.L. Kuznetsov, T.F.S. Silva, J.J.R. Fraústo da Silva, A.J.L. Pombeiro, Trends in properties of para-substituted 3-(phenylhydrazo)pentane-2,4-diones, J. Phys. Org. Chem., 2011, 24, 764-773.  http://dx.doi.org/10.1002/poc.1824

37. R. Wanke, M.F.C.G. Silva, S. Lancianesi, T.F.S. Silva, L.M.D.R.S. Martins, C. Pettinari, A.J.L. Pombeiro, Synthesis and Coordination Chemistry of a New N4-Polydentate Class of Pyridyl-Functionalized Scorpionate Ligands: Complexes of FeII, ZnII, NiII, VIV, PdII and Use for Heterobimetallic Systems, Inorg. Chem., 2010, 49, 7941-7952. http://dx.doi.org/10.1021/ic100966u

36. C. Dinoi, M.F.C.G. Silva, E.C.B.A. Alegria, P. Smole?ski, L.M.D.R.S. Martins, R. Poli, A.J.L. Pombeiro, Molybdenum complexes bearing the tris(1-pyrazolyl)methanesulfonate ligand: synthesis, characterization and electrochemical behaviour, Eur. J. Inorg. Chem., 2010, 16, 2415-2424. http://dx.doi.org/10.1002/ejic.201000018

35. T.F.S. Silva, K.V. Luzyanin, M.V. Kirillova, M.F.C.G Silva, L.M.D.R.S. Martins, A.J.L. Pombeiro, Novel scorpionate and pyrazole dioxovanadium complexes, catalysts for carboxylation and peroxidative oxidation of alkanes, Adv. Synth. Cat., 2010, 352, 171-187. http://dx.doi.org/10.1002/adsc.200900660

34. A.M. Kirillov, E.C.B.A. Alegria, M.F.C.G. Silva, L.M.D.R.S. Martins, C. Sousa, A.J.L. Pombeiro, Synthesis, characterization and redox behaviour of benzoyldiazenido- and oxorhenium complexes bearing N,N- and S,S-type ligands, Inorg. Chim. Acta, 2010, 363, 1269-1274. http://dx.doi.org/10.1016/j.ica.2009.08.030

33. T.F.S. Silva, G.S. Mishra, M.F.G. Silva, R. Wanke, L.M.D.R.S. Martins, A.J.L. Pombeiro, CuII complexes bearing the 2,2,2-tris(1-pyrazolyl)ethanol or 2,2,2-tris(1-pyrazolyl)ethyl methanesulfonate scorpionates. X-ray structural characterization and application in the mild catalytic peroxidative oxidation of cyclohexane, Dalton Trans., 2009, 42, 9207-9215.  http://dx.doi.org/10.1039/b911990f

32. S. Contaldi, C. Di Nicola, F. Garau, Y.Y. Karabach, L.M.D.R.S. Martins, M. Monari, L. Pandolfo, C. Pettinari, A.J.L. Pombeiro, New coordination polymers based on trinuclear triangular [Cu3(?3-OH)(?-pz)3]2+ units and unsaturated carboxylates. Molecular structures, electrochemical behaviour and catalytic peroxidative oxidation of cycloalkanes, Dalton Trans., 2009, 4928-4941. http://dx.doi.org/10.1039/b823370e

31. G.S. Mishra, T.F.S. Silva, L.M.D.R.S. Martins, A.J.L. Pombeiro, Scorpionate V(III-V) Complexes as Catalyst Precursors for Solvent-free Cyclohexane Oxidation with Dioxygen, Pure Appl. Chem., 2009, 81, 1217-1227. http://dx.doi.org/10.1351/PAC-CON-08-10-08

30. C. Di Nicola, F. Garau, Y.Y. Karabach, L.M.D.R.S. Martins, M. Monari, L. Pandolfo, C. Pettinari, A.J.L. Pombeiro, Trinuclear Triangular Copper(II) Clusters. Synthesis, Electrochemical Studies and Catalytic Peroxidative Oxidation of Cycloalkanes, Eur. J. Inorg. Chem., 2009, 666-676. http://dx.doi.org/10.1002/ejic.200800842

29. R. Wanke, P. Smolenski, M.F.C. Guedes da Silva, L.M.D.R.S. Martins, A.J.L. Pombeiro, Cu(I) complexes bearing the new sterically hindered and coordination flexible tris(3-phenyl-1-pyrazolyl)methanesulfonate (TpmsPh) ligand and  the water-soluble phosphine 1,3,5-triaza-7-phosphaadamantane (PTA) or related ligands, Inorg. Chem., 2008, 47, 10158-10168. http://dx.doi.org/10.1021/ic801254b

28. G.S. Mishra, E.C.B.A. Alegria, L.M.D.R.S. Martins, J.J.R. Fraústo da Silva, A.J.L. Pombeiro, Cyclohexane oxidation with dioxygen catalyzed by supported pyrazole rhenium complexes, J. Mol. Cat. A: Chem, 2008, 285, 92-100.  http://dx.doi.org/10.1016/j.molcata.2008.01.022

27. T.F.S. Silva, E.C.B.A. Alegria, L.M.D.R.S. Martins, A.J.L. Pombeiro, Scorpionate Vanadium, Iron and Copper Complexes as Selective Catalysts for the Peroxidative Oxidation of Cyclohexane under Mild Conditions, Adv. Synth. Cat., 2008, 350, 706-716.  http://dx.doi.org/10.1002/adsc.200700529

26. F. Marchetti, C. Pettinari, R. Pettinari, A. Cerquetella, A. Cingolani, E.J. Chan, K. Kozawa, B.W. Skelton, A.H. White, R. Wanke, M.L. Kuznetsov, L.M.D.R.S. Martins, A.J.L. Pombeiro, Areneruthenium(II) 4-Acyl-5-pyrazolonate Derivatives: Coordination Chemistry and Reactivity, Inorg. Chem., 2007, 46, 8245-8257. http://dx.doi.org/10.1021/ic700394r

25. T.F.S. Silva, L.M.D.R.S. Martins, M.F.C. Guedes da Silva, A.J.L. Pombeiro, Bis[tris(1-pyrazolyl)methane-?3N,N',N'']copper(II) chloride methanol disolvate, Acta Cryst., 2007, E63, m1979. http://dx.doi.org/10.1107/S1600536807024671

24. E.C.B.A. Alegria, M.V. Kirillova, L.M.D.R.S. Martins, A.J.L. Pombeiro, Pyrazole and Tris(pyrazolyl)methane Rhenium Complexes as Catalysts for Ethane and Cyclohexane Oxidations, Appl. Catal. A-Gen., 2007, 317, 43-52. http://dx.doi.org/10.1016/apcata.2006.09.038

23. E.C.B.A. Alegria, L.M.D.R.S. Martins, M. Haukka, A.J.L. Pombeiro, Rhenium Complexes of Tris(pyrazolyl)methanes and Sulfonate Derivative, Dalton Trans., 2006, 4954-4961. http://dx.doi.org/10.1039/b611209a

22. T.F.S. Silva, L.M.D.R.S. Martins, A.J.L. Pombeiro, Redox Behaviour of a Tris(pyrazolyl) methanesulfonate Vanadium Complex, A Preliminary Study, Portugaliae Electrochim. Acta, 2006, 24, 257-259. ISSN 0872-1904. http://www.scielo.oces.mctes.pt/scielo.php?pid=S0872-19042006000200007&script=sci_abstract

21. E.C.B.A. Alegria, L.M.D.R.S. Martins, M.F.C. Guedes da Silva, A.J.L. Pombeiro, Syntheses and Properties of Re(III) Complexes Derived from Hydrotris(1-pyrazolyl)methanes. Molecular Structure of [ReCl2(HCpz3)(PPh3)][BF4], J. Organomet. Chem., 2005, 690, 1947-1958. http://dx.doi.org/10.1016/j.jorganchem.2004.11.005

20. A.I.F. Venâncio, M.F.C. Guedes da Silva, L.M.D.R.S. Martins, A.J.L. Pombeiro, Allenylidene Iron(II) Complexes and their Deprotonation, Nucleophilic Addition Reactions, and Cathodic Protonation toward Alkynyl Derivatives: A Chemical and Electrochemical Study, Organometallics, 2005, 24, 4654-4665.

19. E.C.B.A. Alegria, S.M.P.R.M. Cunha, L.M.D.R.S. Martins, M.F.C. Guedes da Silva, A.J.L. Pombeiro, Comparative Electrochemical Behaviour of the Complexes trans-[Mo(NCN){NCNC(O)R}(dppe)2]Cl (R = Et or Ph) and trans-[Mo(NCN)Cl(dppe)2][BF4], Portugaliae Electrochim. Acta, 2004, 22, 19?23, ISSN 0872-1904.  http://www.scielo.oces.mctes.pt/scielo.php?pid=S0872-19042004000100003&script=sci_abstract

18. A.I.F. Venâncio, L.M.D.R.S. Martins, J.J.R. Fraústo da Silva, A.J.L. Pombeiro, Reactions of Cyclic and Linear Alkynols with a Phosphinic Iron(II) Centre, Inorg. Chem. Comm., 2003, 6, 94-96. http://dx.doi.org/10.1016/S1387-7003(02)00690-1

17. L.M.D.R.S. Martins, E.C.B.A. Alegria, D.L. Hughes, J.J.R. Fraústo da Silva, A.J.L. Pombeiro, Syntheses and Properties of Hydride-cyanamide and Derived Hydrogen-cyanamide Complexes of Molybdenum(IV). Crystal Structure of [MoH2(NCNH2)2(Ph2PCH2CH2PPh2)2][BF4]2, Dalton Trans., 2003, 3743-3750.

16. A.I.F. Venâncio, L.M.D.R.S. Martins, A.J.L. Pombeiro, Allenylidene and Derived Alkynyl Complexes of Iron(II) with the {FeBr(Et2PCH2CH2PEt2}+ Centre, J. Organomet. Chem., 2003, 684, 315-321. http://dx.doi.org/10.1016/S0022-328X(03)00766-6

15. A.I.F. Venâncio, L.M.D.R.S. Martins, A.J.L. Pombeiro, Electrochemical Study of Alkynyl Fe(II) complexes, Portugaliae Electrochim. Acta, 2003, 21, 85-90. ISSN 0872-1904.

14. A.I.F. Venâncio, M.L. Kuznetsov, M.F.C. Guedes da Silva, L.M.D.R.S. Martins, J.J.R. Fraústo da Silva, A.J.L. Pombeiro, Metal-hydride Bond Activation and Metal-metal Interaction in Dinuclear Iron Complexes with Linking Dinitriles: A Synthetic, Electrochemical and Theoretical Study, Inorg. Chem., 2002, 41, 6456-6467. http://dx.doi.org/10.1021/ic025835k

13. M.F.C. Guedes da Silva, L.M.D.R.S. Martins, J.J.R. Fraústo da Silva, A.J.L. Pombeiro, Redox Potential-structure Relationships in 18- and 17-Electron Mononitrile (or Monocarbonyl) Diphosphine Complexes of Re and Fe, Collect. Czech. Chem. Commun., 2001, 66, 139?154. http://dx.doi.org/10.1135/cccc20010139

12. E.C. Bastos, L.M.D.R.S. Martins, J.J.R. Fraústo da Silva, A.J.L. Pombeiro, Redox Behaviour of a Biscyanamide-dihydride Mo Complex, a Preliminary Study, Portugaliae Electrochim. Acta, 2001, 19, 357-360. http://dx.doi.org/10.4152/pea.200103357

11. A.I.F. Venâncio, L.M.D.R.S. Martins, J.J.R. Fraústo da Silva, A.J.L. Pombeiro, Redox Behaviour of Alkynol-derived Allenylidene Complexes of Iron(II), Portugaliae Electrochim. Acta, 2001, 19, 361-366, ISSN 0872-1904. http://dx.doi.org/10.4152/pea.200103361

10. L.M.D.R.S. Martins, J.J.R. Fraústo da Silva, A.J.L. Pombeiro, R.A. Henderson, D.J. Evans, F. Benetollo, G. Bombieri, R.A. Michelin, Syntheses, Properties and Mössbauer Studies of Cyanamide and Cyanoguanidine Complexes of Iron(II). Crystal Structures of trans-[FeH(NCNH2)(Ph2PCH2CH2PPh2)2][BF4] and trans-[Fe(NCNEt2)2(Et2PCH2CH2PEt2)2][BF4]2, Inorg. Chim. Acta, 1999, 291, 39-48. http://dx.doi.org/10.1016/S0020-1693(99)00021-3

9. L.M.D.R.S. Martins, M.T. Duarte, A.M. Galvão, C. Resende, A.J.L. Pombeiro, R.A. Henderson, D.J. Evans, Syntheses, Properties and Mössbauer Studies of Mono- and Di-nitrile Phosphine Complexes of Iron(II). Crystal Structures of trans-[Fe(NCR)2(Et2PCH2CH2PEt2)2][BF4]2 (R = Me or CH2C6H4OMe-4), J. Chem. Soc., Dalton Trans., 1998, 3311-3317. http://dx.doi.org/10.1039/A804193H

8. L.M.D.R.S. Martins, M.F.C. Guedes da Silva, I. Marques, J.J.R. Fraústo da Silva, M.C.N. Vaz, A.J.L. Pombeiro, Fast-atom Bombardment (FAB) Mass Spectra of Nitrile or Cyanamide Complexes with the {M(Ph2PCH2CH2PPh2)2}n+ (M = Fe or Re) Metal Sites. Application to Reactions Induced under FAB Conditions, Rapid Comm. Mass Spectrom. 1996, 10, 447-454. http://dx.doi.org/10.1002/(SICI)1097-0231(19960315)10:4<447:AID-RCM490>3.0.CO;2-N  

7. L.M.D.R.S. Martins, A.J.L. Pombeiro, R.A. Henderson, Stopped-flow Mechanistic Study of Bromide Substitution by an Organonitrile at an Iron(II) Phosphinic Centre; a ?-Electron Driven Process, Inorg. Chim. Acta, 1996, 250, 311-315. http://dx.doi.org/10.1016/S0020-1693(96)05240-1

6. S.S.P. Almeida, M.T. Duarte, L.M.D. Ribeiro, F. Gormley, A.M. Galvão, J.J.R. Fraústo da Silva, A.J.L. Pombeiro, Formation of vinyl and dithioformate metallacycles by insertion of an ester-functionalized alkyne or carbon disulfide into an Fe-H bond: crystal structure of cis-[Fe(CH=CHCOOMe)(Ph2PCH2CH2PPh2)2][BF4], J. Organomet. Chem., 1996, 524, 63-66. http://dx.doi.org/10.1016/S0022-328X(96)06290-0

5. L.M.D.R.S. Martins, A.J.L. Pombeiro, Structure-potential relationships for the dinitrile complexes trans-[Fe(NCR)2(Et2PCH2CH2PEt2)2][BF4]2, Portugaliae Electrochim. Acta, 1996, 14, 151-155. ISSN 0872-1904.

4. L.M.D. Ribeiro, M.A.N.D.A. Lemos, A.J.L. Pombeiro, P. Sobota, Electrochemical study of some chloro complexes of titanium, molybdenum, iron, aluminium or tin in high oxidation states, Russian J. Electrochem., 1995, 31, 1009-1015 (edição russa original: Elektrokhimiya, 1995, 31, 1093-1099). 

3. L.M.D. Ribeiro, A.J.L. Pombeiro, Structure-potential relationships for the nitrile complexes trans-[FeBr(NCR)(Et2PCH2CH2PEt2)2][BF4], Portugaliae Electrochim. Acta, 1995, 13, 329-333. ISSN 0872-1904.

2. L.M.D. Ribeiro, M.A.N.D.A. Lemos, J.J.R. Fraústo da Silva, A.J.L. Pombeiro, Electroreduction of methylisocyanide at a low-oxidation state iron centre, Portugaliae Electrochim. Acta, 1993, 11, 117-120. ISSN 0872-1904.

1. T. Sá e Melo, J. Cirne de Castro, L. Ribeiro, J. Conte, D. Lawrence, M. Bazin and R. Santus, Degradation of crystallins from a psoriatic patient undergoing PUVA therapy, FEBS Letters, 1990, 268, 72-74. http://dx.doi.org/10.1016/0014-5793(90)80975-O Catalysts 202010, 419; doi:10.3390/catal10040419  


1. L. Martins, Scorpionate Complexes as Catalysts for Alkane Functionalization, ALICERCES - Revista de Investigação, Ciência e Tecnologia, Edições Colibri/IPL, Lisboa, Ano II, nº 2 (Dezembro 2008 - Maio 2009), pp.107-116.ISSN 1645-7943. - invited paper http://www.ipl.pt/sites/default/files/alicerces_2.pdf